Determining heavy metal concentrations and physicochemical properties in wastewater

R. Hailu, Mekonen Nibret
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Abstract

Wastewaters are frequently harmful to both the environment and human health since they are both directly and indirectly released into surface waters. The aim of this study was to determine physicochemical properties and to assess the levels of heavy metals in wastewater. Wastewater samples were collected from Koka and Mojo from the Oromia region, Ethiopia. Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) was used to determine the concentration of these heavy metals. The conductivity of wastewater obtained from the Mojo and Koka sites ranged from 1141.33 to 1498.32µS/cm and 1066.33 to 1243.72µS/cm, respectively. The maximum and minimum BOD effluent from Mojo and Koka sites were 1044.78mg/L and 794.73mg/L, and 883.00mg/L and 772.67mg/L, respectively. The COD value was found to range between 1466.08mg/L and 1615.38mg/L in the Mojo area and 1352.65mg/L to 1530.83mg/L in the Koka area, respectively. High BOD levels are a sign of contamination and could indicate a lack of oxygen for living things. In every one of the sample sites, it exceeds the recommended level. High COD levels suggest hazardous conditions and the presence of organic compounds that are resistant to biological processes. The maximum TDS of the effluents, which is more than the recommended limit, were found to be 2417.08mg/L and 2317.06mg/L in Mojo and Koka areas, respectively. Overall concentrations of heavy metals (As, Pb, B, Zn, Cd Hg, Cu, Ni, Co, Fe, Mn and Cr) in mg/L were found to be in the permissible range except for mercury (Hg). The wastewater had heavy metal Hg that was higher than the limits advised by the WHO and US EPA. The studies’ findings imply that the effluents are harmful by nature and need considerable treatment before being released into the ecosystem on land.
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测定废水中重金属浓度及理化性质
废水往往对环境和人类健康都有害,因为它们直接或间接排放到地表水中。本研究的目的是确定废水的理化性质并评估其重金属含量。废水样本采集自埃塞俄比亚奥罗米亚地区的Koka和Mojo。采用电感耦合等离子体发射光谱(ICP-OES)测定了这些重金属的浓度。Mojo和Koka的废水电导率分别为1141.33 ~ 1498.32µS/cm和1066.33 ~ 1243.72µS/cm。Mojo和Koka的BOD出水最大值和最小值分别为1044.78mg/L和794.73mg/L, 883.00mg/L和772.67mg/L。Mojo地区和Koka地区的COD值分别在1466.08 ~ 1615.38mg/L和1352.65 ~ 1530.83mg/L之间。高BOD水平是污染的标志,可能表明生物缺乏氧气。在每个样本站点中,它都超过了建议水平。高COD水平表明环境危险,存在抵抗生物过程的有机化合物。Mojo和Koka地区的最大TDS分别为2417.08mg/L和2317.06mg/L,超过了建议限值。除汞(Hg)外,所有重金属(As、Pb、B、Zn、Cd、Hg、Cu、Ni、Co、Fe、Mn、Cr)的mg/L浓度均在允许范围内。废水中重金属汞的含量高于世界卫生组织和美国环保署建议的限量。研究结果表明,这些废水本质上是有害的,在排放到陆地生态系统之前需要进行大量处理。
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