Dielectric Properties of (Ba, Sr, Ca)TiO3 Ceramics for Tunable Microwave Devices

Bing Qin, D. Jin, Jinrong Cheng, Z. Meng
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Abstract

(Ba0.9-xSrxCa0.1)TiO3 (x=0.25~0.5) and (Ba0.6-ySr0.4Cay)TiO3 (y=0.05~0.2) ceramics were fabricated by the mixed-oxide method. All BSCT specimens owned dense and homogeneous structure without the second phase. By comparing the properties of (Ba0.9-xSrxCa0.1)TiO3 and (Ba0.6-ySr0.4Cay)TiO3, we found that the influence of Ba/Sr ratio on Curie temperature is greater than that of Ba/Ca ratio. The increasing of Ca content could decrease the dielectric loss and dielectric constants, but it would decrease the tunability as well. (Ba0.55Sr0.4Ca0.05)TiO3 and (Ba0.5Sr0.4Ca0.1)TiO3 are expected to be the candidate materials for microwave tunable devices, whose tunability, dielectric constant and loss were 24.1%, 4300, 0.28% and 16.5%, 3200, 0.096% respectively.
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可调谐微波器件用(Ba, Sr, Ca)TiO3陶瓷的介电性能
采用混合氧化法制备了(Ba0.9-xSrxCa0.1)TiO3 (x=0.25~0.5)和(Ba0.6-ySr0.4Cay)TiO3 (y=0.05~0.2)陶瓷。所有BSCT试样均具有致密均匀的结构,不存在第二相。通过比较(Ba0.9-xSrxCa0.1)TiO3和(Ba0.6-ySr0.4Cay)TiO3的性能,我们发现Ba/Sr比对居里温度的影响大于Ba/Ca比。钙含量的增加会降低介质损耗和介电常数,但也会降低可调性。(Ba0.55Sr0.4Ca0.05)TiO3和(Ba0.5Sr0.4Ca0.1)TiO3有望成为微波可调谐器件的候选材料,其可调谐性、介电常数和损耗分别为24.1%、4300、0.28%和16.5%、3200、0.096%。
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