Memory Effect Involving Fib-Induced Ga-Nanocrystals In GaAs/AIGaAs Heterojunction FETs

H. Kim, T. Noda, H. Sakaki
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Abstract

Nanofabrication using focused-ion-beam (FIB) technique has made it possible to fabricate various nano-structures where electrons exhibit low dimensionality and/or the Coulomb blockade effect [l]. However, single-electron effects are normally observed in these structures only at very low temperature, since the room temperatureoperation is possible only in nm-size devices. Here, we investigate effects of implanted impurities on the transport of AlGaAdGaAs FET by measuring its voltage-current characteristics after FIB implantation with high dose (>10'5cm-2) Ga ions. As the dose increases, the Ga ions are expected to form gallium nanocrystals in the vicinity of projected raqge (Rp) which trap electrons between the channel and the control gate. This process is interesting as .a new phenomenon in nano-structures and may be important as a method to form new single electronmemory devices at room temperature. In this work, we show that a novel memory function can be achieved by using the charge-transfer process between FIB-induced Ga-nanocrystals and a nearby channel. Samples used for transport properties are prepared on a modulation-doped GaAs/AlGaAs single heterostructure grown by molecular beam epitaxy (MBE) on a (001) oriented GaAs substrate. The implantation is performed at room temperature using the lOOkV focused Ga ion beam and 2 ~ 1 0 ' ~ c m ~ dose density. Figure l(a) shows a schematic view of the device structure used in the experiment. It has a channel whose nominal width (W) and length (L) are both 1 ,U m. lOOkV Ga+ ions focused to a spot size of 0.2 , U m are implanted (black lines in Fig. l(b)). The effective channel confined by FIB induced depletion layers is less than 0.2 ,U m. We investigate the drain current Id and the device capacitance C as a function of gate voltage Vg. The reproducible hysteresis is measured on the current (Id)-voltage (Vg) experiments when the control gate voltage is swept back and forth with respect to the source (Fig.2). No hysteresis has been observed in other Ga beam induced FETs fabricated in the same process with a low dose density. There is a possibility that heavy dose of Ga ions has led to the formationof Ga-nanocrystals near the channel (Fig. 1 (c)).Therefore, it is likely that the hysteresis is caused by the charge transfer between Ga-nanocrystals and the effective channel. Note that Ga nanocrystals are formed on the channel due to the unfocused ions and/or lateral spreading of scattered ions. Ga nanocrystals produced as an three-dimensionally confined quantum dot embedded in a capacitor, separated from effectivechannel by a shottky barrier and from the other by a non-doped AlGaAs spacer layer. In this memory device the potentialchange elc associated with the transfer of a single electron is a non-negligible quantity This transistor, in which channel region is locally constricted by highdose Ga-FIB implantation, may, therefore, operate as a kind of single-electron memory device at room temperature with controllable injection, storage, and removal of an electron from Gananocrystals. The injection of an electron occurs from the laterally confined channel via direct tunneling only when the control gate is forward biased with respect to the source and drain. Then the stored charge screens the control gate charge and decreases the conduction in the channel as the threshold voltage of the transistor gets more positive. In summary, a memory effect caused by the direct tunneling into FIB induced nanocrystals is found to yield a hysteresis in the conduction of GaAdAlGaAs FETs. [ l ] Y Hirayama, K. Ploog : J. Appl. Phys. 72, p3022 (1992).
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GaAs/AIGaAs异质结fet中光纤诱导的ga纳米晶体记忆效应
使用聚焦离子束(FIB)技术的纳米制造使得制造各种纳米结构成为可能,其中电子表现出低维度和/或库仑封锁效应[1]。然而,单电子效应通常只能在非常低的温度下在这些结构中观察到,因为室温操作只能在纳米尺寸的器件中实现。本研究通过测量高剂量(bbb10′5cm-2) Ga离子FIB注入后AlGaAdGaAs FET的电压-电流特性,研究了注入杂质对AlGaAdGaAs FET输运的影响。随着剂量的增加,镓离子有望在投影栅(Rp)附近形成镓纳米晶体,从而在通道和控制栅之间捕获电子。这一过程是纳米结构中一种有趣的新现象,可能是在室温下形成新的单电子存储器件的重要方法。在这项工作中,我们证明了一种新的记忆功能可以通过使用光纤诱导的镓纳米晶体和附近通道之间的电荷转移过程来实现。在(001)取向的GaAs衬底上通过分子束外延(MBE)生长出调制掺杂的GaAs/AlGaAs单一异质结构,制备了用于输运性能的样品。在室温下使用lOOkV聚焦的镓离子束和2 ~ 10′~ cm ~剂量密度进行注入。图1 (a)显示了实验中使用的器件结构示意图。它具有标称宽度(W)和长度(L)均为1 μ m的通道。lOOkV Ga+离子聚焦到0.2 μ m的光斑尺寸(图1 (b)中的黑线)。受FIB耗尽层限制的有效通道小于0.2 μ m。我们研究了漏极电流Id和器件电容C作为栅电压Vg的函数。当控制栅极电压相对于源来回扫频时,在电流(Id)-电压(Vg)实验上测量了可重复的磁滞(图2)。采用相同工艺制备的其他低剂量密度的镓束流诱导场效应管未发现迟滞现象。有可能是大剂量的Ga离子导致通道附近形成了Ga纳米晶体(图1 (c))。因此,迟滞很可能是由于镓纳米晶体与有效通道之间的电荷转移引起的。注意,由于未聚焦离子和/或分散离子的横向扩散,在通道上形成了Ga纳米晶体。镓纳米晶体是一种嵌入在电容器中的三维受限量子点,它与有效通道之间由一个短势垒隔开,与另一个由一个未掺杂的AlGaAs间隔层隔开。在这种存储器件中,与单电子转移相关的电势变化elc是一个不可忽略的量。这种晶体管的通道区域被高剂量的Ga-FIB注入局部收缩,因此可以在室温下作为一种单电子存储器件工作,可以从ganan晶体中可控地注入、存储和移除电子。只有当控制栅相对于源极和漏极正向偏置时,电子才能通过直接隧穿从侧向受限通道注入。然后,当晶体管的阈值电压变得更正时,存储的电荷屏蔽控制栅极电荷并降低通道中的导通。综上所述,直接隧穿到FIB诱导的纳米晶体中所引起的记忆效应在GaAdAlGaAs fet的传导中产生了滞后。[1]张志强,张志强。物理学72,p3022(1992)。
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