Kinetic Study for Janus Green Dye Adsorption from Aqueous Solutions Using Iraqi Bauxite Clay and its Composite

Abbas Jumaa Sahal, A. Mohammed Abbas
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Abstract

Clays are considered important natural materials in the field of water purification, including bauxite clay (BAU) and its prepared and activated composite (BAU/CMC-AC) with carboxymethyl cellulose polymer. The ad-sorbent surfaces are characterized by FTIR and XRD techniques. The adsorp-tion of green janus (JG) from an aqueous solution with bauxite and its compo-site were studied under the influence of different conditions of the weight and size of adsorbed surface particles, contact time and temperature. The results were found to be: contact time (90, 45) min for maximum quantity adsorbed of (JG) dye on bauxite and its composite respectively. The experimental data were tested on pseudo 1st- and 2nd-order kinetic models. It was shown to apply more with the pseudo-2nd order kinetic model for both adsorbents. It also showed that the highest removal percentage were (78%, 88.5 %) for the bauxite surface and its composite (BAU, BAU/CMC-AC) at the preferred temperature
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伊拉克铝土矿粘土及其复合材料对黄绿色染料的吸附动力学研究
粘土是水净化领域中重要的天然材料,包括铝土矿粘土(BAU)及其与羧甲基纤维素聚合物制备的活化复合材料(BAU/CMC-AC)。采用FTIR和XRD技术对吸附表面进行了表征。研究了铝土矿及其复合材料在吸附表面颗粒的重量、大小、接触时间和温度等不同条件下对水溶液中绿毒的吸附性能。结果表明:(JG)染料在铝土矿及其复合材料上的最大吸附时间分别为(90,45)min。在拟一级和二级动力学模型上对实验数据进行了验证。结果表明,准二级动力学模型对两种吸附剂都更适用。在优选温度下,铝土矿表面及其复合材料(BAU、BAU/CMC-AC)的去除率分别为78%、88.5%
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