Optimisation and Kinetics of Rubber Seed Oil Biodiesel Production

W. Aisabor, Y. Lukman, A. Otaru, A. E. Anakhu, S. Otoikhian
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Abstract

Due to the increasing yearn to go environment friendly, keen interest has been placed on biofuels, this leads to further studies and research in biofuels. A search for suitable vegetable/plant oil that can work just as fossil fuels and be ecofriendly was made. Hence, the study of this work investigates the production of biodiesel from non-edible Hevea brasiliensis oil. The process was catalysed by two-step acid base transesterification. Reaction parameters, such as reaction temperature and time were studied. The yield conversion of biodiesel was found to be 50.2% under the optimum conditions of 1.0 wt % NaOH and 6:1 methanol: oil molar ratio at 60°C for a reaction time of 75 min. The kinetic study was carried out at various temperatures. The conversion of triglycerides into methyl esters obeys the pseudo first-order mechanism. The reaction-rate constants and activation energies were determined. The physical and chemical characteristics of H. brasiliensis and biodiesel were determined and compared with standard value.
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橡胶籽油生物柴油生产工艺优化及动力学研究
由于人们对环境友好的渴望越来越强烈,人们对生物燃料产生了浓厚的兴趣,这导致了生物燃料的进一步研究和研究。寻找合适的植物油,可以像化石燃料一样工作,是生态友好的。因此,本研究探讨了从不可食用的巴西橡胶树油中生产生物柴油的方法。该工艺采用两步酸碱酯交换催化。研究了反应温度、反应时间等参数。在NaOH质量分数为1.0 wt %,甲醇:油摩尔比为6:1,反应时间为75 min的条件下,生物柴油的收率为50.2%。甘油三酯转化为甲酯遵循伪一级机理。测定了反应速率常数和活化能。测定了巴西螺和生物柴油的理化特性,并与标准值进行了比较。
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