Failure analysis on Mobile Phone Batteries and Accessories

Zhi Jin, H. Nishikawa, Y. Chan
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Abstract

In recent years, the demand of lithium ion battery is enlarged because of enormous capacity and free from memory effect which was widely applied to electronic devices. However, the explosion of Samsung Note7 battery arouses public attention in of lithium ion battery‘s safety issue. In addition, the capacity of battery will drop during usage time, one battery can only work for two years normally. In this study, we will find caused the explosion and capacity decrease of battery during usage process. The methodology started with thermal shock test to accelerate the aging time of battery. During the testing, the capacity change of battery after each 200 h was recorded. After the test, each component including the protective circuit, cathode and anode were analyzed respectively. From protective circuit aspects, the corrosion of PCB by hydrofluoric acid will cause malfunction of the circuit leading to overcharging or over-discharging. Since the decomposition of SEI on anode leading to exfoliation of graphite. The generation of fresh SEI will consume lithium ion inside the electrolyte leading to capacity decrease. Moreover, the phenomenon why some batteries will be swollen up during usage has been analyzed from chemical reaction aspect. Finally, this study can be used to offer good suggestions to manufacturers in improving the reliability of lithium ion battery.
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手机电池及配件失效分析
近年来,锂离子电池因其巨大的容量和不受记忆效应的影响而被广泛应用于电子器件中,对锂离子电池的需求量越来越大。然而,三星Note7电池爆炸事件引起了公众对锂离子电池安全问题的关注。另外,电池的容量在使用过程中会下降,一块电池只能正常工作两年。在本研究中,我们将发现电池在使用过程中会引起爆炸和容量下降。该方法从加速电池老化的热冲击试验入手。在测试过程中,记录每200h后电池的容量变化。试验结束后,对保护电路、阴极、阳极等各部件分别进行了分析。从保护电路方面来说,氢氟酸对PCB的腐蚀会造成电路故障,导致过充或过放。由于SEI在阳极上的分解导致石墨的剥落。新SEI的产生会消耗电解液中的锂离子,导致容量下降。并从化学反应的角度分析了部分电池在使用过程中膨胀的原因。最后,本研究可以为制造商提高锂离子电池的可靠性提供很好的建议。
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