Microstructure and Mechanical Properties of Purity Aluminum Refined with Salt Containing Ti and B Elements

Heng Zhang, T. Xuan, G. Shao, Luo-ping Xu
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引用次数: 4

Abstract

The microstructure and mechanical properties of purity aluminum refined with salt containing Ti and B elements have been studied in detail with Optical Microscope and MTS (Mechanical Testing and Simulation). The salt containing weight ratio of 22.2 Ti : 1 B has the most refining effect on the purity aluminum with the finest structure and the best mechanical properties, meanwhile it also possesses the advantages of short reacting time (within 5 minutes) and long fading time (more than 20 hours). The refining effect of the salt increases with the content of Ti and B in the melting and the refining mechanism is mainly contributed to the heterogeneous nuclei of more fine TiAl3 particles dispersed in the melting, which come from the reaction between the salt and aluminum. Purity B contained salt has little or no directly refining effect, However, B contained salt has indirect refining effect on the purity aluminum when it is added simultaneously with Ti contained salt, this may be due to that the dispersive and fine boride (TiB2) could be taken as the heterogeneous nuclei for TiAl3 particle, and then prevents the coarsening of the TiAl3 particle.
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含钛、B元素盐精制纯铝的组织与力学性能
采用光学显微镜和MTS(力学测试与模拟)对含钛、B元素盐精制纯铝的微观组织和力学性能进行了详细研究。重量比为22.2 Ti: 1b的盐对纯铝的精炼效果最好,具有最精细的组织和最佳的力学性能,同时还具有反应时间短(5分钟以内)和褪色时间长(20小时以上)的优点。盐的精炼效果随着熔体中Ti和B含量的增加而增强,其精炼机理主要是由于盐与铝的反应产生了分散在熔体中的更细的TiAl3颗粒的非均相核。纯B盐对纯铝的精炼作用很小或没有直接的精炼作用,而当B盐与Ti盐同时加入时,对纯铝有间接的精炼作用,这可能是由于分散的细硼化物(TiB2)可以作为TiAl3颗粒的非均相核,从而阻止了TiAl3颗粒的粗化。
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