Surface-enhanced Raman scattering by CdS quantum dots

A. Milekhin, L. Sveshnikova, T. Duda, N. Surovtsev, S. Adichtchev, D. Zahn
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引用次数: 9

Abstract

Surface enhanced Raman scattering is studied in nanostructures with CdS quantum dots formed by using the Langmuir-Blodgett technology. Features related to longitudinal optical phonons of quantum dots are observed in the Raman spectra of both free-standing CdS quantum dots and the dots embedded in an organic matrix. Strong enhancement of intensity (about factor of 700) of Raman scattering by free quantum dots is observed by deposition of silver clusters onto the nanostructure surfaces. The dependence of the Raman intensity on the excitation energy is resonant with a maximum at the energy corresponding to the maximal absorption of Ag clusters.
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CdS量子点表面增强拉曼散射
采用Langmuir-Blodgett技术,研究了CdS量子点在纳米结构中的表面增强拉曼散射。在独立的CdS量子点和嵌入有机矩阵的量子点的拉曼光谱中观察到与量子点纵向光学声子相关的特征。通过在纳米结构表面沉积银团簇,观察到自由量子点拉曼散射强度的增强(约为700倍)。喇曼强度对激发能的依赖是共振的,在Ag团簇最大吸收能量对应的能量处达到最大值。
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