Three-component approach to hexahydropyrido-[2,1-b] [1,3]-oxazin-6-ones and cyclohex-2-en-1-ones based on polyfluoroalkyl-3-oxo esters, methyl ketones, and 3-amino-1-propanol

VIII Information school of a young scientist Central Scientific Library of the Urals Branch of the Russian Academy of Science Pub Date : 2020-12-16 DOI:10.32460/ISHMU-2020-8-0011
S. O. Kushch, M. V. Goryaeva, Y. Burgart, O. G. Khudina, V. I. Saloutin
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Abstract

Найдены конкурентные пути трехкомпонентной циклизации полифторалкил-3-оксоэфиров и метилкетонов с 3-амино-1-пропанолом в зависимости от условий. Показано, что в 1,4-диоксане реакции приводят к гексагидро- пиридо-[2,1-b][1,3]-оксазин-6-онам, а в этаноле к – циклогекс-2-ен-1-онам.редложен механизм превращений полифторалкил-3-оксоэфиров и метилкетонов с 3-амино-1-пропанолом.
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基于多氟烷基-3-氧酯、甲基酮和3-氨基-1-丙醇的六氢吡啶-[2,1-b][1,3]-恶嗪-6-酮和环己-2-烯-1-酮的三组分制备方法
根据条件，已经发现了三部分聚氟乙烯-3-羟色胺和甲基酮的竞争性循环。= =反应= =在1.4 - dioxan中，反应导致六聚氰胺-皮利多-[2.1 -b] -[1.3]多氟拉基-3-羟色胺和甲基酮与3-氨基-1-丙烷的转化机制是罕见的。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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VIII Information school of a young scientist Central Scientific Library of the Urals Branch of the Russian Academy of Science
VIII Information school of a young scientist Central Scientific Library of the Urals Branch of the Russian Academy of Science
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