{"title":"The 355 nm Photolysis of Methyl Nitrite","authors":"C. G. Atkins, G. Hancock","doi":"10.1155/LC.9.195","DOIUrl":null,"url":null,"abstract":"Single photon laser induced fluorescence (LIF) has been used to study the NO fragment \nproduced in its ground electronic state from the 355 nm photolysis of CH3ONO. \nPopulations of rotational, vibrational, spin-orbit and lambda doublet components have \nbeen measured. The results are in broad agreement with previous two photon LIF \nstudies, and confirm the dynamics of the process in which the NO fragment departs from \nan essentially planar CONO framework with non-statistical energy partitioning in the \ninternal states of the products.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"42 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"13","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Laser Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/LC.9.195","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 13
Abstract
Single photon laser induced fluorescence (LIF) has been used to study the NO fragment
produced in its ground electronic state from the 355 nm photolysis of CH3ONO.
Populations of rotational, vibrational, spin-orbit and lambda doublet components have
been measured. The results are in broad agreement with previous two photon LIF
studies, and confirm the dynamics of the process in which the NO fragment departs from
an essentially planar CONO framework with non-statistical energy partitioning in the
internal states of the products.
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