Enhancement of Thermoelectric Figure of Merit in Ternary Silver Thallium Tellurides by Controlling the Carrier Concentration

K. Kurosaki, K. Goto, H. Muta, S. Yamanaka
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Abstract

We tried to improve the thermoelectric figure of merit of a ternary silver thallium telluride, Ag9TlTe5, by controlling the carrier concentration. We studied the effect of deviation from the stoichiometric composition by measuring the thermoelectric properties from room temperature to slightly below the melting temperature of polycrystalline Ag9TlTe5 with different nominal compositions. A minimal compositional deviation of Ag9TlTe5 improved the power factor while the thermal conductivity remained extremely low, leading to an enhancement of the thermoelectric figure of merit
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控制载流子浓度提高三元碲化银铊的热电优值
我们试图通过控制载流子浓度来改善三元碲化银铊Ag9TlTe5的热电优值。通过测量不同标称成分Ag9TlTe5多晶在室温至略低于熔点范围内的热电性能,研究了化学计量成分偏差对Ag9TlTe5的影响。Ag9TlTe5的最小成分偏差提高了功率因数,而导热系数仍然极低,从而提高了热电性能
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