Chapter 2. Surface Engineering of Boron Nitride Nanoplatelets for Thermal Conductivity Enhancement of Polymers

Yu Chen, P. Jiang, J. Kong, Xingyi Huang
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Abstract

Boron nitride nanoplatelets (BNNP) have great potential for the improvement of the thermal conductivity of polymers due to their ultra-high thermal conductivity and excellent insulation properties. Herein, we provide a review on surface engineering of BNNP and their applications in polymer composites. This chapter begins with the introduction of the structural features and properties of BNNP. The preparation methods of BNNP are classified as ‘top-down’ and ‘bottom-up’ approaches. BNNP can be further chemically modified by introducing different functional groups onto the surface in order to improve compatibility between the BNNP and the polymer matrices. Thermally conductive polymer composites based on BNNP have developed rapidly from the development of novel preparation methods and the design of sophisticated internal microstructures.
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第二章。氮化硼纳米片增强聚合物导热性的表面工程研究
氮化硼纳米片(BNNP)由于其超高的导热性能和优异的保温性能,在提高聚合物导热性能方面具有很大的潜力。本文综述了BNNP的表面工程及其在高分子复合材料中的应用。本章首先介绍了BNNP的结构特点和性质。BNNP的制备方法分为“自上而下”和“自下而上”两种方法。BNNP可以通过在表面引入不同的官能团来进一步进行化学修饰,以改善BNNP与聚合物基质之间的相容性。新型制备方法的开发和内部微结构的设计使基于BNNP的导热聚合物复合材料得到了迅速发展。
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Chapter 1. 2D High-κ Dielectric Ceramic Nanoplatelets for Polymer Nanocomposite Capacitors Chapter 2. Surface Engineering of Boron Nitride Nanoplatelets for Thermal Conductivity Enhancement of Polymers Chapter 4. Graphite Nanoplatelet–Carbon Nanotube Hybrids for Electrical Conducting Polymer Composites Chapter 5. 2D Nanomaterial-based Polymer Composite Electrolytes for Lithium-based Batteries Chapter 3. Transition Metal Carbide (MXene)–Polymer Nanocomposites
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