Analytical Investigation on the Homogeneous Nucleation in a Mono-Component and Bi-Component Droplet

Xi Xi, Hong Liu, Chang Cai, M. Jia, Weilong Zhang
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Abstract

The work attempts to analyze the performance of homogeneous nucleation by using the non-equilibrium thermodynamics theory and the classical nucleation theory. A nucleation rate graph was constructed under a wide range of operating temperature conditions. The results indicate that the superheat limit temperature (SLT) estimated by the modified homogeneous nucleation sub-model is in good agreement with the experimental results. The nucleation rate increases exponentially with the liquid temperature rise when the liquid temperature exceeds the SLT under atmospheric pressure. The superheated temperature needed to trigger the bubble nucleation decreases with the elevated ambient pressure.
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单组分和双组分液滴均匀成核的分析研究
本文试图运用非平衡态热力学理论和经典成核理论对均匀成核的性能进行分析。在较宽的工作温度条件下,构造了成核速率图。结果表明,修正均匀形核子模型估算的过热极限温度与实验结果吻合较好。常压下,当液温超过SLT时,成核速率随液温的升高呈指数增长。触发气泡成核所需的过热温度随着环境压力的升高而降低。
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