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Molecular Mechanism of Water Transport Through Cellulose Cell Wall Matrix 纤维素细胞壁基质中水转运的分子机制
Jiaqi Sun, Xinrong Zhang
In plant living tissue, water can flow across cells by different paths, through cell membranes (transcellular path) and plasmodesmata (symplastic path), or through the continuous cell walls matrix (apoplastic path). The relative contribution of these three paths in living tissue is currently unclear and could vary according to species, tissue developmental stage or physiological conditions. Experiments suggested that apoplastic water movement predominates during transpiration. The objective of this study was to investigate the hydraulic process of cellulose cell wall pathway. The effective pore diameter for water flow through the primary wall matrix is between 2 and 20nm. Inside the cell wall polymer porous, there exist hydrophilic/hydrophobic crystal surfaces based on structure anisotropic. Besides, hydrogen bonding and electrostatic interaction and van der Waals (vdW) dispersion force play an important role in water transport inside the Nano cellulose porous. Therefore, the molecular dynamics simulation was applied to reveal the molecular mechanism of surface boundary effect together with various driving force during water passing through cellulose cell wall matrix Nano channel.
在植物活组织中,水可以通过不同的途径流过细胞,通过细胞膜(跨细胞途径)和胞间连丝(共塑途径),或通过连续的细胞壁基质(胞外途径)。这三种途径在活组织中的相对作用目前尚不清楚,可能因物种、组织发育阶段或生理条件而异。实验表明,在蒸腾过程中,外体水分运动占主导地位。本研究的目的是研究纤维素细胞壁途径的水力过程。水通过原生壁基质的有效孔径在2 ~ 20nm之间。聚合物细胞壁内部多孔,存在基于结构各向异性的亲疏水晶体表面。此外,氢键、静电相互作用和范德华(vdW)分散力在纳米纤维素孔内的水输运中起重要作用。因此,通过分子动力学模拟,揭示了水通过纤维素细胞壁基质纳米通道时表面边界效应及各种驱动力的分子机制。
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引用次数: 0
Research on Thermal Properties of Insulator-Metal Transition at Room Temperature in Sm1-xCaxMnO3 Sm1-xCaxMnO3绝缘子-金属室温相变热性能研究
Ruxia Chang, Desong Fan, Qiang Li
The high-purity electron-doped manganites Sm1-xCaxMnO3 nanopowder were prepared by the solid-state reaction method, then the bulk material were obtained through granulation, molding, calcining, grinding and polishing. SCMO nanoparticles with 200 nm were obtained by the sol-gal process. The phase and surface morphology of these materials were characterized by X-ray diffraction and Scanning electron microscope and other experiments. The variable resistivity of the bulk materials were measured by two-wire method in the temperature range of 100–420K. The thermal conductivity was measured by the Laser Flash method. The results show that different doping ratios can change the phase transition temperature of the metal-insulation state. The temperature changed from 0 to 50 °C. The TMI could be regulated to room temperature. When the temperature is high than the TMI, it performs as metal state, on the contrary, it performs as an insulating state.
采用固相反应法制备了高纯掺杂锰酸盐Sm1-xCaxMnO3纳米粉体,并通过造粒、成型、煅烧、研磨、抛光等工艺得到了块状材料。采用溶胶-gal法制备了粒径为200 nm的SCMO纳米颗粒。通过x射线衍射、扫描电镜等实验对材料的物相和表面形貌进行了表征。采用双线法测量了块状材料在100-420K温度范围内的变电阻率。用激光闪蒸法测定了热导率。结果表明,不同掺杂比例可以改变金属绝缘态的相变温度。温度从0℃变化到50℃。TMI可以调节到室温。当温度高于TMI时,它表现为金属态,反之则表现为绝缘态。
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引用次数: 0
Non-Newtonian Droplet Generation in a Flow-Focusing Microchannel 流动聚焦微通道中的非牛顿液滴生成
Chundong Xue, Zhong-ping Sun, Yongjiang Li, K. Qin
The emergence of microfluidic droplets offers new opportunities to advance biomedical engineering, food production, and energy storage applications. These applications always involve complex fluids exhibiting obvious non-Newtonian behavior. Droplet generation has been extensively addressed, while the complete understanding of droplet generation in non-Newtonian fluid system is still nascent. Here, we present the study of non-Newtonian droplet generation in a flow-focusing microchannel. Polyethylene oxide aqueous solutions are used as the dispersed phase, while olive oil serves as the continuous phase to induce the generation. The molecular weight of polymer is constant while the concentrations are varied from dilute to semi-dilute regimes that are rarely explored in existing studies. The main features of non-Newtonian droplet generation are first identified, after which the concentration-dependent dripping to jetting transitions are clarified. The effects of shear thinning and elasticity on droplet generation are then separately investigated. We finally propose a scaling relation to predict the primary droplet size with the satellite droplets neglected. These results can not only extend the fundamental theory of droplet microfluidics but also facilitate the practical applications.
微流控液滴的出现为推进生物医学工程、食品生产和能源储存应用提供了新的机会。这些应用总是涉及具有明显非牛顿行为的复杂流体。液滴的产生已经得到了广泛的研究,而对非牛顿流体系统中液滴产生的完整理解仍处于萌芽阶段。在这里,我们提出了非牛顿液滴在流动聚焦微通道中产生的研究。采用聚氧聚乙烯水溶液作为分散相,橄榄油作为连续相诱导生成。聚合物的分子量是恒定的,而浓度从稀到半稀变化,这在现有的研究中很少探索。首先确定了非牛顿液滴产生的主要特征,然后澄清了随浓度变化的滴向喷射的转变。然后分别研究了剪切变薄和弹性对液滴生成的影响。最后,我们提出了一个尺度关系来预测初级液滴的大小,忽略卫星液滴。这些结果不仅扩展了液滴微流体的基本理论,而且有利于实际应用。
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引用次数: 0
Topological Phonon Polaritons for Thermal Radiation Control 热辐射控制的拓扑声子极化子
B. X. Wang, C. Y. Zhao
Topological phonon polaritons (TPhPs) are highly localized edge modes that can achieve a strong confinement of electromagnetic waves and are topologically protected to be immune to impurities and disorder. In this paper, we theoretically study the topological phonon polaritons (TPhPs) in one-dimensional (1D) dimerized silicon carbide (SiC) nanoparticle (NP) chains, as an extension of the celebrated Su-Schrieffer-Heeger (SSH) model. We analytically calculate the band structure and complex Zak phase for such chains by taking all near-field and far-field interactions into account. It is found that the 1D dimerized chain supports nontrivial topological states as long as the dimeriza-tion parameter β > 0.5 and the long-range interactions are weak, although the system is non-Hermitian. By analyzing the distribution of eigenmodes and their participation ratios (PRs), we comprehensively study the effects of disorder on the band structure and midgap modes. We reveal that such TPhPs are very robust under high-degree disorders and even enhanced by the disorder. Through a finite-size scaling analysis, we show this enhancement can be attributed to Anderson localization scheme. These topological phonon polaritonic states provide an efficient interface for thermal radiation control in the mid-infrared.
拓扑声子极化子(TPhPs)是一种高度局域化的边缘模式,可以实现对电磁波的强约束,并且受到拓扑保护,可以免受杂质和无序的影响。本文从理论上研究了一维二聚碳化硅纳米颗粒链中的拓扑声子极化子(TPhPs),作为著名的Su-Schrieffer-Heeger (SSH)模型的扩展。我们通过考虑所有近场和远场相互作用,分析计算了这种链的能带结构和复杂的Zak相。结果表明,尽管该体系是非厄米体系,但只要二聚化参数β > 0.5,该一维二聚化链支持非平凡拓扑态,且远程相互作用较弱。通过分析本征模的分布及其参与比(pr),我们全面研究了无序对带结构和中隙模的影响。我们发现这种TPhPs在高度障碍下非常健壮,甚至被疾病增强。通过有限尺寸缩放分析,我们表明这种增强可归因于安德森定位方案。这些拓扑声子极化态为中红外热辐射控制提供了一个有效的界面。
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引用次数: 0
Electrokinetic Energy Conversion in Conical Nanochannels: Regulation Effect due to Conicity 锥形纳米通道中的电动能量转换:由于锥形的调节效应
Fang Qian, Deng Huang, Wenyao Zhang, Wenbo Li, Qiuwan Wang, Cunlu Zhao
Electrokinetic energy conversion being a promising clean energy production technology utilizes the electric double layer (EDL) in a nanochannel to convert hydrodynamic energy to electrical power. The previous research mainly focuses on the electrokinetic energy conversion in straight nanochannels. In this work, we perform a systematic investigation of electrokinetic energy conversion in a conical nanochannel. For this purpose, a multiphysical model consisting of the Planck-Nernst-Poisson equation and Navier-Stokes equation was formulated and solved numerically. Particularly, we discover various regulation effects in the electrokinetic energy conversion in conical nanochannels that the energy conversion characteristics (streaming potential, streaming current and I-V characteristics) are different for a forward pressure difference and a backward pressure difference of the same magnitude. These regulation effects are found to be caused by the conicity of channel. Then the effects of the channel conicity, applied pressure difference and the surface charge density on the performance of electrokinetic energy conversion are discussed in details. It is generally shown that the regulation effects are enhanced by increasing the conicity, pressure difference and surface charge density. The conclusions from this work can serve as important reference and guidelines for the design and operation of electrokinetic energy conversion devices.
电动能转换是一种很有前途的清洁能源生产技术,它利用纳米通道中的双电层(EDL)将水动力转化为电能。以往的研究主要集中在直线型纳米通道中的电动能转换。在这项工作中,我们对锥形纳米通道中的电动能转换进行了系统的研究。为此,建立了由Planck-Nernst-Poisson方程和Navier-Stokes方程组成的多物理模型,并对其进行了数值求解。特别是,我们发现了锥形纳米通道中电动能量转换的各种调节效应,在相同大小的正向压差和反向压差下,能量转换特性(流势、流电流和I-V特性)是不同的。这些调节作用是由沟道的锥形度引起的。然后详细讨论了通道锥度、外加压差和表面电荷密度对电动能转换性能的影响。一般表明,增大锥度、压差和表面电荷密度可以增强调节效果。所得结论可为电动能量转换装置的设计和运行提供重要的参考和指导。
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引用次数: 0
Molecular Dynamics Simulation of Boiling Behavior of Nanofluid With Various Wettability Nanoparticle on Hydrophobic Surface 不同润湿性纳米颗粒纳米流体在疏水表面沸腾行为的分子动力学模拟
Xunyan Yin, Min-li Bai, Chengzhi Hu, Jizu Lv, Yubai Li
Molecular dynamics simulation is performed to investigate the rapid boiling of nanofluid with the variation nanoparticle wettabilities above hydrophobic surface. Four fluids are selected: base fluid (fluid 1), nanofluid with nanoparticle wettability less than (fluid 2), equal tofluid 3) and greater than (fluid 4) surface wettability. It should be noted that nanoparticle is deposited on the surface in this paper. Results show that nanofluid responds rapid boiling faster than base fluid. For fluid 4, the efficiency in heat transfer is enhanced due to the improvement of surface wettability. While for fluid 2 and 3, the surface wettability is deteriorated by the depositional nanoparticle. The heat flux is strengthened, but argon temperature and evaporation number reduce, and thus fluid 2 and 3 are not beneficial for heat transfer.
通过分子动力学模拟研究了纳米流体的快速沸腾与纳米颗粒在疏水表面润湿性的变化。选择四种流体:基础流体(流体1)、纳米颗粒润湿性小于(流体2)、等于流体3)和大于(流体4)表面润湿性的纳米流体。值得注意的是,在本文中,纳米颗粒沉积在表面。结果表明,纳米流体对沸点的反应比基液快。对于流体4,由于表面润湿性的改善,传热效率得到了提高。而对于流体2和流体3,纳米颗粒的沉积使其表面润湿性恶化。热流密度增强,但氩气温度和蒸发次数降低,流体2和流体3不利于传热。
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引用次数: 2
The Spreading Characteristics and Temperature Evolution of Droplet Impact on Cold Superhydrophilic Surface 液滴撞击冷超亲水表面的扩散特性及温度演化
Jiang Chun, Tingting Hao, Yansong Chen, Yingjie Zheng, Xuehu Ma, Z. Lan
Droplet impact phenomena and thin liquid film flow are widespread in nature, industrial production and daily life. The spreading characteristics and temperature evolution of the liquid film after droplet impact are the key controlling factors in many industrial heat transfer processes. Constructing a thin micro-nano structured superhydrophilic surface on a metal surface is a promising approach to achieving heat transfer enhancement. Therefore, in this paper, we experimentally investigated the hydraulic characteristics and temperature distribution evolution of water droplet impact on cold superhydrophilic surface using high-speed imaging and infrared thermal imaging techniques. During the droplet spreading on superhydrophilic surface, there is an inertial-force-dominant rapid spreading regime followed by the friction-dominant slow spreading regime. It is observed that a precursor film forms in the radial direction. The results show that the droplet spreading diameter is positively correlated with the We number, increasing as the weber number becomes larger. The spreading diameter decreases as the wall temperature decreases, but the effect of temperature is not obvious compared with that of impact weber number. For temperature evolution, a low temperature center area forms at the impact center and a ring-shaped high temperature zone is observed first for droplet impact on cold superhydrophilic surfaces. Along spreading radial direction, the temperature distribution shows an uphill to downhill curve with its gradient inverted in sign near the high temperature zone. Then the high temperature ring disappears and the liquid film temperature shows a monotonically decreasing trend along the radial direction. The duration time of high temperature ring shortens with the increase of We number and decrease of wall temperature. Meanwhile, in order to reveal the reasons for the formation of special temperature distribution, CFD numerical simulation is adopted to analyze the mechanism of ring-shaped high temperature zone’s formation. CFD numerical simulation demonstrates that the temperature evolution law is in good agreement with the experiment results. The temperature distribution of high temperature ring is caused by uneven distribution of the liquid film thickness due to the superwetting properties of superhydrophilic surface. This work is of great significance for further understanding and provides new sights of the liquid film flow on superhydrophilic surface in heat transfer process. Furthermore, it has certain reference significance for the spray and heat transfer process in engineering practice.
液滴撞击现象和薄液膜流动现象在自然界、工业生产和日常生活中广泛存在。液滴撞击后液膜的扩散特性和温度演变是许多工业传热过程中的关键控制因素。在金属表面构建薄微纳结构的超亲水表面是一种很有前途的增强传热的方法。因此,本文利用高速成像和红外热成像技术,实验研究了水滴撞击冷超亲水表面的水力特性和温度分布演变。液滴在超亲水表面的扩散过程中,先有以惯性力为主的快速扩散阶段,然后是以摩擦为主的缓慢扩散阶段。观察到在径向上形成前驱体膜。结果表明:液滴扩散直径与韦伯数呈正相关,随着韦伯数的增大而增大;随着壁面温度的降低,扩散直径减小,但温度的影响与冲击韦伯数的影响相比不明显。在温度演化上,液滴撞击超亲水冷表面时,在撞击中心形成低温中心区,首先形成环状高温区。沿径向扩散方向,温度分布呈由上至下的曲线,在高温区附近温度梯度呈倒号。然后高温环消失,液膜温度沿径向呈单调下降趋势。高温环的持续时间随着We数的增加和壁温的降低而缩短。同时,为了揭示特殊温度分布形成的原因,采用CFD数值模拟的方法对环形高温区形成的机理进行了分析。CFD数值模拟结果表明,温度演化规律与实验结果吻合较好。高温环的温度分布是由于超亲水表面的超润湿特性导致液膜厚度分布不均匀造成的。这项工作对进一步认识超亲水表面传热过程中的液膜流动具有重要意义,并为研究超亲水表面传热过程提供了新的视角。对工程实践中的喷淋传热过程具有一定的参考意义。
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引用次数: 0
Study on the Flow and Heat Transfer Characteristics of Micro-Scale Droplets and Fluid on Dynamic Liquid Film Condition by Lattice Boltzmann Method 用晶格玻尔兹曼方法研究微尺度液滴和流体在动态液膜条件下的流动和传热特性
Yichao He, Yan Li, Z. Ding, Han Yuan, N. Mei
The lab on a chip is of great value in the analytical chemistry, biology and pharmacy. So that it is very important to study the formation and control of droplet in chips. The fluid flowing under the condition of dynamic liquid film is researched innovatively in this paper. Its inspiration is derived from bionics (fish skin, etc.), which has a broad application prospect in reducing the resistance in water and weakening the heat transfer. Dynamic liquid film refers to the dynamic thin liquid layer with the hydrophilic property on the surface of wall under the pressure of outside fluid flow. The insolubility between liquid film and fluid creates a relatively stable flowing environment. In this paper, the formation and influencing factors of the droplet in the microfluidic chip are studied by the Lattice Boltzmann method (LBM), and the flow and heat transfer characteristics of fluid in microchannel is studied with microfluidic chip as the carrier under the condition of insoluble dynamic liquid film existing on the wall surface. LBM has certain advantages in boundary processing, parallel operation and tracing phase interface automatically. Using SC model of LBM (for two component flow), the process of formation and movement of the droplet in microfluidic chip are simulated numerically after verified by Laplace‘s law. The result shows that the hydrophobic characteristics between the discrete phase and the wall surface and increased flow rate of the continuous phase will decrease the droplets’ volume and increase the producing frequency. In addition, the fluid flow in the microchannel is simulated under the condition of insoluble dynamic liquid film on the wall surface. The simulation result shows that when the fluid flow rate increases, the friction loss decreases and the heat transfer capacity decreases with the existence of the liquid film. The lower the dissolution trend between fluid and liquid film is, the greater the variation trend of fluid parameters will be. By comparing the results of experiment and simulation, the consistent results are obtained.
芯片实验室在分析化学、生物学和药学等领域具有重要的应用价值。因此,研究芯片中液滴的形成与控制具有十分重要的意义。本文创新性地研究了流体在动态液膜条件下的流动。其灵感来源于仿生学(鱼皮等),在降低水中阻力、弱化传热等方面有着广阔的应用前景。动态液膜是指在外界流体流动压力作用下,壁表面具有亲水性的动态薄液层。液膜与流体之间的不溶性创造了一个相对稳定的流动环境。本文采用格子玻尔兹曼方法(Lattice Boltzmann method, LBM)研究了微流控芯片中液滴的形成及影响因素,研究了壁面存在不溶性动态液膜条件下,以微流控芯片为载体的微通道中流体的流动及换热特性。LBM在边界处理、并行运算和相位界面自动跟踪等方面具有一定的优势。采用双组分流的SC模型,对微流控芯片中液滴的形成和运动过程进行了数值模拟,并得到拉普拉斯定律的验证。结果表明,离散相与壁面之间的疏水特性和连续相流速的增加将减小液滴的体积,提高液滴的产生频率。此外,还模拟了壁面不溶动液膜条件下微通道内的流体流动。仿真结果表明,当流体流量增大时,由于液膜的存在,摩擦损失减小,换热能力减小。流体与液膜的溶解趋势越低,流体参数的变化趋势越大。将实验结果与仿真结果进行了比较,得到了一致的结果。
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引用次数: 0
Mechanisms of Heat and Mass Transfer for Thin-Film Evaporation With Velocity Slip and Temperature Jump 具有速度滑移和温度跳变的薄膜蒸发传热传质机理
Xiu Xiao, C. Yan, Yulong Ji
Velocity slip and temperature jump at the solid-liquid interface are important phenomena in microchannel heat transfer. A comprehensive mathematical model considering both velocity slip condition and temperature jump at the solid-liquid interface is developed to understand the mechanisms of heat and mass transfer during thin-film evaporation in this paper. The model structure is established based on the lubrication theory, Clausius-Clapeyron equation and Young-Laplace equation. To better formulate the film evaporation process, three dimensionless parameters representing the effects of slip length coefficient, temperature jump and wall superheat degree respectively, are introduced in the present model. The analytical solution provides insight of film thickness and heat transfer characteristics for the evaporating thin film. It shows that as the slip length and temperature jump coefficient decrease, the length of evaporating thin film region is shortened and the location of maximum heat flux moves closer to the initial evaporating point. The effect of slip condition on heat flux is small, but the increase of temperature jump can reduce the peak heat flux significantly. Furthermore, the analysis on the three thermal resistances which are caused by temperature jump, conduction through liquid film and evaporation on liquid-vapor interface result in a better understanding for effective heat transfer during thin-film evaporation.
固液界面速度滑移和温度跳变是微通道传热中的重要现象。为了理解薄膜蒸发过程的传热传质机理,建立了考虑速度滑移和固液界面温度跳变的综合数学模型。基于润滑理论、Clausius-Clapeyron方程和Young-Laplace方程建立了模型结构。为了更好地描述膜的蒸发过程,在模型中引入了三个无量纲参数,分别代表滑移长度系数、温度跳变和壁面过热度的影响。解析解提供了蒸发薄膜的膜厚和传热特性。结果表明,随着滑移长度和温度跳变系数的减小,蒸发薄膜区域的长度缩短,最大热流密度的位置向初始蒸发点靠近。滑移条件对热流密度的影响较小,但温度跳变的增加可以显著降低峰值热流密度。此外,通过对温度跳变、液膜传导和液汽界面蒸发三种热阻的分析,可以更好地理解薄膜蒸发过程中的有效传热。
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引用次数: 0
Numerical Investigation of Flow Boiling in a Manifold Microchannel Heat Sink With Conjugate Heat Transfer 具有共轭传热的流形微通道散热器流动沸腾的数值研究
Zhi-chuan Sun, Yang Luo, Junye Li, Wei Li, Jingzhi Zhang, Zhengjiang Zhang, Jie Wu
The manifold microchannel heat sink receives an increasing number of attention lately due to its high heat flux dissipation. Numerical investigation of boiling phenomena in manifold microchannel (MMC) heat sinks remains a challenge due to the complexity of fluid route and the limitation of numerical accuracy. In this study, a computational fluid dynamics (CFD) approach including subcooled two-phase flow boiling process and conjugate heat transfer effect is performed using a MMC unit cell model. Different from steady-state single phase prediction in MMC heat sink, this type of modeling allows for the transient simulation for two-phase interface evolution during the boiling process. A validation case is conducted to validate the heat transfer phenomenon among three phases. Besides, this model is used for the assessment of the manifold dimensions in terms of inlet and outlet widths at the mass flux of 1300 kg/m2·s. With different ratios of inlet-to-outlet area, the thermal resistances remain nearly stable.
流形微通道散热器由于其高的热通量耗散,近年来受到越来越多的关注。由于流体路径的复杂性和数值精度的限制,流形微通道(MMC)散热器中沸腾现象的数值研究一直是一个挑战。在本研究中,采用MMC单元胞模型,采用计算流体动力学(CFD)方法计算了过冷两相流沸腾过程和共轭传热效应。与MMC热沉的稳态单相预测不同,该模型允许对沸腾过程中两相界面演化进行瞬态模拟。通过实例验证了三相换热现象。此外,还利用该模型对质量通量为1300 kg/m2·s时的进出口宽度进行了多维度评价。在不同的进出口面积比下,热阻基本保持稳定。
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引用次数: 0
期刊
ASME 2019 6th International Conference on Micro/Nanoscale Heat and Mass Transfer
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