N incorporation into ALD HfO/sub 2/ gate dielectric using ion implantation [MOSFET application]

H. Li, T. Pompl, C. Young, T. Rhoad, J. Saulters, J. Peterson, M. Gardner, G.A. Brown, G. Bersuker, P. Zeitzoff, J. Price, P. Hung, A. Diebold, H. Huff
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Abstract

A fabrication process for HfON, using ion implantation of N/sub 2/ in ALD HfO/sub 2/, was demonstrated. Results showed that a good quality HfON could be formed by N/sub 2/ implantation, which suggests nitrogen implantation can be an alternative high-k nitridation technique. This process was successfully integrated into a traditional CMOS flow and the electrical and reliability results of HfON, as compared to HfO/sub 2/, showed 10 times less Vt shift in the pulsed Id-Vg measurement and up to 70% gate leakage reduction. In addition, EOT, electron/hole mobility, TDDB and subthreshold slope of HfON also performed better than those of HfO/sub 2/. A model is proposed to explain the result by attributing the improvement to the reduction of defect states (oxygen vacancies) in the HfO/sub 2/ film by the presence of N in the HfON film.
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离子注入ALD HfO/sub - 2/栅极电介质中氮的掺入[MOSFET应用]
介绍了在ALD HfO/ sub2 /中注入N/ sub2 /离子制备HfON的工艺。结果表明,氮/亚氮/氮注入可形成高质量的HfON,表明氮注入可作为一种替代的高钾氮化技术。该工艺成功地集成到传统的CMOS流程中,与HfO/sub 2/相比,HfON的电学和可靠性结果显示,在脉冲ids - vg测量中,Vt移减少了10倍,栅极泄漏减少了70%。此外,HfON的EOT、电子/空穴迁移率、TDDB和亚阈值斜率也优于HfO/ sub2 /。提出了一个模型来解释这一结果,该模型将改善归因于氮的存在使HfO/ sub2 /膜中的缺陷态(氧空位)减少。
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