Cobalt Phosphates and Applications

R. Marzouki, M. A. Sayed, M. Graia, M. Zid
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引用次数: 5

Abstract

Cobalt phosphates with open framework present various physical performances in relation to their structures. In fact, the development of new materials that could potentially be ionic conductors or ion exchangers led us to examine the Co-P-O and A-Co-P-O crystallographic systems (A: monovalent cation) and their different methods of synthesis. This work consists first of all in highlighting the crystalline phases of cobalt phosphates. Indeed, many works related to the discovery of some of these materials with interesting properties, in particular ionic conductivity, motivated our research and encouraged us to collect several cobalt phosphates and to correlate structure-physical properties in particular electrical properties. crystal lattice. In addition, these modelizations are based on the structural data of the crystal. Since the measurements are often performed on ceramics, it is also necessary to take into account the effect of the relative density of the ceramic: effect of the microstructure.
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磷酸钴及其应用
具有开放骨架的磷酸钴表现出与其结构相关的各种物理性能。事实上,可能成为离子导体或离子交换剂的新材料的开发使我们研究了Co-P-O和A-Co-P-O晶体学系统(A:单价阳离子)及其不同的合成方法。这项工作首先包括突出磷酸钴的结晶相。事实上,许多与发现这些具有有趣性质的材料有关的工作,特别是离子电导率,激励了我们的研究,并鼓励我们收集几种磷酸钴,并将结构-物理性质特别是电性能联系起来。晶格。此外,这些模型是基于晶体的结构数据。由于测量通常是在陶瓷上进行的,因此也有必要考虑到陶瓷的相对密度的影响:微观结构的影响。
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