Comment: Reply to Comment on “Dynamics of the B Π3(0u+) and a Π3(1u) States of Chlorine by Laser Induced Fluorescence”

Laser Chemistry Pub Date : 1900-01-01 DOI:10.1155/1994/48678
E. Martínez, F. Basterrechea, B. Cabañas, P. Puyuelo, M. R. López
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Abstract

The comment of Billy et al.1 on our paper about the dynamics of the B and A states of chlorine2 emphasizes mainly two points: a) our results about the radiative decay rate of the B state of Cl2 are incorrect, because our experimental system is unable to measure the true long lifetimes of this state; b) both A Π 3 ( 1 u ) and Π 1 ( 1 u ) states contribute to the Coriolis predissociation in the B state, in contradiction with our mechanism, which excludes the Π 1 ( 1 u ) state.
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评论:回复“氯的B Π3(0u+)和a Π3(1u)态激光诱导荧光动力学”评论
Billy等人对我们关于氯气B态和A态动力学的论文的评论主要强调两点:A)我们关于氯气B态的辐射衰减率的结果是不正确的,因为我们的实验系统无法测量出这种状态的真正长寿命;b) A Π 3 (1u)和Π 1 (1u)态都有助于b态的科里奥利预解,这与我们排除Π 1 (1u)态的机制相矛盾。
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