P. Stanić, Darko P Ašanin, M. Vasić, T. Soldatović, Biljana M Šmit
{"title":"KINETICS OF THE REACTION OF AN ARYLIDENE 2-THIOHYDANTOIN DERIVATIVE WITH SOME Pd(II) COMPLEXES","authors":"P. Stanić, Darko P Ašanin, M. Vasić, T. Soldatović, Biljana M Šmit","doi":"10.46793/sbt28.497s","DOIUrl":null,"url":null,"abstract":"Reactions of 3-(benzylideneamino)-2-thioxoimidazolidin-4-one with some palladium complexes (PdCl2, Pd(DMSO)2Cl2 and K2PdCl4) were monitored with NMR spectroscopy, which is used as a convenient and practical tool for determining the kinetic parameters of the reactions. Rate constants of the reactions were determined and reactivity of the complexes towards the 2-thiohydantoin derivative was compared.","PeriodicalId":106266,"journal":{"name":"1st INTERNATIONAL SYMPOSIUM ON BIOTECHNOLOGY: Proceedings","volume":"97 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"1st INTERNATIONAL SYMPOSIUM ON BIOTECHNOLOGY: Proceedings","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.46793/sbt28.497s","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Reactions of 3-(benzylideneamino)-2-thioxoimidazolidin-4-one with some palladium complexes (PdCl2, Pd(DMSO)2Cl2 and K2PdCl4) were monitored with NMR spectroscopy, which is used as a convenient and practical tool for determining the kinetic parameters of the reactions. Rate constants of the reactions were determined and reactivity of the complexes towards the 2-thiohydantoin derivative was compared.