Photovoltage transients in GaAs/InGaAs solar cells (Presentation Recording)

Roman Holubenko, A. Yakovliev, S. Kondratenko
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Abstract

A study of the photovoltaic properties of the GaAs-based solar cells with InGaAs quantum wire had been conducted. The research included the investigation of the photovoltage rise and decay transients, spectral photovoltage dependences at different temperatures. The objects investigated were GaAs-based solar cells with InGaAs quantum wire (QWR) embedded into space-charge-region of p-i-n junction. Samples with different In content and size of InGaAs nanoobjects had been created using molecular beam epitaxy. Unlike the reference cell, the ones containing the InGaAs QWR had shown higher sensitivity in the energy range 1.2 - 1.38 eV. This is caused by the spatial separation of electron-hole (e-h) pairs excited in the QWR due to band-to-band transition. Under selective excitation of the e-h pairs only in the InGaAs quantum wire the photovoltage rise transient is slower compared to the e-h generation in GaAs. This effect is explained by charge carriers release from the InGaAs quantum well into delocalized states of the surrounding GaAs. It was determined that the InGaAs quantum wires increase the recombination rate of the non-equilibrium carriers in the temperature range 80 to 290 K, which means that the quantum wires are the additional recombination centers.
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GaAs/InGaAs太阳能电池的光电压瞬态(演讲记录)
采用InGaAs量子线对gaas基太阳能电池的光电性能进行了研究。研究了不同温度下光电压的上升和衰减瞬态,光谱光电压的依赖关系。研究对象是将InGaAs量子线(QWR)嵌入到p-i-n结的空间电荷区中的gaas基太阳能电池。采用分子束外延法制备了不同In含量和尺寸的InGaAs纳米物。与参考电池不同,含有InGaAs QWR的电池在1.2 ~ 1.38 eV的能量范围内表现出更高的灵敏度。这是由于QWR中由于带间跃迁而激发的电子-空穴(e-h)对的空间分离造成的。仅在InGaAs量子线中选择性激发e-h对时,光电压上升瞬态比GaAs中的e-h产生要慢。这种效应可以用从InGaAs量子阱释放的载流子进入周围GaAs的离域态来解释。结果表明,在80 ~ 290 K的温度范围内,InGaAs量子线提高了非平衡载流子的复合速率,表明量子线是额外的复合中心。
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