Removal of malachite green by poly acrylic beads

Nooraldeen Muwafaq Ali, Ammar Jasim Mohammed
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Abstract

This work investigates removing the Malachite Green (MG) dye, the poly acrylic hydrogel beads used as a surface to adsorb the dye, the isotherm of adsorption was examined and aspects that influence it, like increasing heat, adding salt, the influence of dry beads and effect of shaking. according to the results, the effect of the adsorption has been found that it is matched to the Friendlish equation much more than Langmuir and Temkin equations. A positive relationship between the adsorption process and the increase in temperature is found that adsorption increases when the temperature increase. Also, the adsorption increased when the salt was added at a temperature (of 20 C0). As that the adsorption doesn’t budge by adding either dry or wet beads of poly acrylic. The thermodynamic function was calculated (ΔH, ΔS, ΔG). The kinetic parameters were examined by the Lagergren equation to first order, for second-order equations either, according to the results of experimental data showing us that the adsorption obeys the pseudo-second order more than the first-order.
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用聚丙烯酸珠去除孔雀石绿
本文研究了去除孔雀石绿(MG)染料,用聚丙烯酸水凝胶珠作为表面吸附染料,考察了吸附等温线以及加热、加盐、干燥珠的影响和震动的影响等方面的影响。结果表明,吸附效应更符合Friendlish方程,而不是Langmuir和Temkin方程。发现吸附过程与温度升高成正相关,吸附量随温度升高而增加。当温度为20℃时,吸附量增加。因此,无论加入干珠还是湿珠,吸附都不会发生变化。计算热力学函数(ΔH, ΔS, ΔG)。采用拉格伦方程(Lagergren equation)对动力学参数进行了一级方程和二级方程的检验,结果表明吸附过程服从伪二级而非一级。
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