Aging in Ferroelectrics, a Drift Approach

Y. Genenko, N. Balke, D. Lupascu
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Abstract

Point defect migration is considered as a mechanism to yield aging in ferroelectrics. Different from magnetic systems, ferroelectric domains can be pinned by free charges at the perimeter of otherwise homogeneous grains or crystals. This clamping is shown to be stronger due to the reorientation of defect dipoles. Clamping stresses are calculated to be in the range of 106 to 107 Pa in a uniaxial model corresponding to experimental values in the model material BaTiO3. Their time dependence is given in a uniaxial model case. An extension to three dimensions is discussed. The values are independent of the type of mobile defect charge carrier, electronic or ionic.
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铁电体的老化,一种漂移方法
点缺陷迁移被认为是铁电体屈服老化的一种机制。与磁性系统不同,铁电畴可以由均匀颗粒或晶体周围的自由电荷固定。由于缺陷偶极子的重定向,这种夹持被证明是更强的。在单轴模型中计算出的夹紧应力范围为106 ~ 107 Pa,与模型材料BaTiO3的实验值相对应。在单轴模型情况下给出了它们的时间依赖关系。讨论了对三维空间的扩展。这些值与移动缺陷电荷载体的类型无关,是电子的还是离子的。
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