Effects of oxide additive on thermoelectricity of FeSi2

S. Sugihara, K. Morikawa, Y. Igarashi, K. Nishiyama
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Abstract

Thermoelectricity has been hot issue in these days, because of environmental problems and energy sources deficit. Moreover, material development for thermoelectricity is now busy in oxide and metal or alloy, basically. However, conclusive materials with good performance have not yet been found in application basis. We have studied oxide-added beta-FeSi2 for these years. Iron disilicide is well known and utilized in relatively higher temperature. In this report, we indicated our successful improvement of performance of beta-FeSi2 added with Ta2O5 showing the figure of merit almost 0.3 times 10-3/K This was obtained by reducing thermal conductivity and electrical resistivity (a half of standard FeSi2)
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氧化物添加剂对FeSi2热电性能的影响
由于环境问题和能源短缺,热电已成为当前研究的热点。此外,目前热电材料的开发主要集中在氧化物和金属或合金方面。但在应用基础上还没有找到性能良好的结论性材料。这些年来,我们一直在研究添加氧化物的β - fesi2。二硅化铁是众所周知的,在相对较高的温度下使用。在这篇报告中,我们指出我们成功地改善了加入Ta2O5的β -FeSi2的性能,其优值几乎是10-3/K的0.3倍,这是通过降低导热系数和电阻率(标准FeSi2的一半)获得的。
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