{"title":"Singlet And Triplet n,π∗ Transitions of Jet-Cooled p-Benzoquinone","authors":"I. Suzuka, M. Sanekata, Mitsuo. Ito, N. Ohta","doi":"10.1155/1994/72592","DOIUrl":null,"url":null,"abstract":"The fluorescence/phosphorescence excitation spectra, the dispersed fluorescence/phosphorescence spectra \nand the sensitized phosphorescence excitation spectrum have been measured for jet-cooled p-benzoquinone. \nThe assignments of vibronic bands in the 1B1g(n-,π∗) ← 1Ag and 1Au(n+,π∗) ← 1Ag transitions \nhave been definitely established. The phosphorescence spectra from vibronic levels of 3Au exhibit a \nfeature of single vibronic level emission. The 3Au ← 1Ag transition was also vibrationally analyzed.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"27 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Laser Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/1994/72592","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
The fluorescence/phosphorescence excitation spectra, the dispersed fluorescence/phosphorescence spectra
and the sensitized phosphorescence excitation spectrum have been measured for jet-cooled p-benzoquinone.
The assignments of vibronic bands in the 1B1g(n-,π∗) ← 1Ag and 1Au(n+,π∗) ← 1Ag transitions
have been definitely established. The phosphorescence spectra from vibronic levels of 3Au exhibit a
feature of single vibronic level emission. The 3Au ← 1Ag transition was also vibrationally analyzed.
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