Technology of conversion of materials of power and oil refining objects

L. Chelyadyn, V. Ribun, V. V. Vizinovych, І. V. Tarasiuk
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引用次数: 1

Abstract

Quantitative and qualitative characteristics of multi-ton materials in Ukraine and in Ivano-Frankivsk region, which Quantitative and qualitative characteristics of multi-ton materials in Ukraine and in Ivano-Frankivsk region, which contain energy components, are given. It is proposed to process water treatment sludges containing petro-leum products by preparing a raw material mixture from the following man-made substances: oil sludge, ash, zeo-lite screenings, calcium-containing compounds and viscous materials. The optimal composition of the raw material mixture is as follows: as a filler for construction products (concrete): ash – 60-65 %, liquid glass s olution – 5-7 %, limestone dust – 3-5 %, organic additives – 7-10 %, soda ash – 10-12 %, which is granulated and heat t reated at 120-140 °C. The research results and technical char acteristics of the obtained granular materials, which are formed from a mixture containing a significant amount of hydrocarbon sludge, have lower strength, but greater porosity and lower thermal conductivity. Granules from a mixture № 4-7 are characterized by higher strength, and due to their properties they belong to the structural and thermal insulation materials. The technology of obtaining a raw material mixture for soda production is based on the LeBlanc process – the interaction in the seco nd stage of sodium sulfate, carbon and calcium carbonate with the formation of calcium sulfide, sodium carbonate and carbon (IV) oxide. It is proposed to prepare a raw mixture for the production of sodium carbonate from sodium sulfate con-taining petroleum product, which is formed by the technology of obtaining oxygen-containing additives, and sludge containing petroleum products, which will provide a high temperature during the soda production process. The processing of sludge from oil refining and energy facilities into granular materials shows that they can be used in the construction industry and soda production, which reduces the energy consumption of the processes of obtaining such materials.
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电力和炼油原料转化技术
给出了乌克兰和伊万诺-弗兰科夫斯克地区含有能源成分的多吨材料的定量和定性特征。提出以油泥、灰分、零沸石筛分、含钙化合物和黏性物质为原料,制备含石油产品水处理污泥的混合原料。原料混合物的最佳组成如下:作为建筑产品(混凝土)的填料:灰分- 60- 65%,液态玻璃溶液-5 - 7%,石灰石粉尘- 3- 5%,有机添加剂-7 - 10%,纯碱-10 - 12%,将其制成颗粒,在120-140℃下加热。研究结果和所获得的颗粒材料的技术特征是,由含有大量碳氢污泥的混合物形成的颗粒材料强度较低,但孔隙率较大,导热系数较低。混合物№4-7的颗粒具有较高的强度,由于它们的性质,它们属于结构和保温材料。制碱原料混合物的获取技术是基于勒布朗过程——硫酸钠、碳和碳酸钙在第二阶段的相互作用,形成硫化钙、碳酸钠和氧化碳。提出以含石油产品的硫酸钠为原料,通过获得含氧添加剂的技术与含石油产品的污泥相结合,制备一种生产碳酸钠的原料混合物,该原料混合物将在苏打生产过程中提供高温。炼油和能源设施的污泥加工成颗粒状材料表明,它们可以用于建筑工业和苏打生产,从而降低了获取此类材料的过程的能耗。
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