Synthesizing and Performance Test of a New Aciding Gelatinizer ZCY-1

Bo Zhou
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Abstract

In order to meet the requirements of high temperature acidizing, a new acid gelatinizer was synthesized by choosing non ionic monomer AM, complex cationic monomer H-DMDAAC, anionic monomer AMPS as starting materials and redox system as initiator in aqueous solution at low temperature. Various factors influencing polymerization reaction were analyzed, the optimum conditions of polymerization were determined, the basic performance of gelling acid was evaluated and its action mechanism was studied. The results show that it has good property to increase viscosity, resistance to high temperature and acid-rock reaction retardation, the viscosity of acidizing fluid of 20% mass fraction can reach 37.5 mPa·s at the high temperature of 150℃ and shearing rate of 170s-1 when the mass fraction of ZCY-1 is 1%; mass fraction of gelling acid remains 11.9% after 60 min’s reaction with limestone, which is 7 times more than that of common acid, it can meet the need of acidizing in high temperature wells.
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新型酸化糊化剂ZCY-1的合成及性能试验
为了满足高温酸化的要求,以非离子单体AM、复合阳离子单体H-DMDAAC、阴离子单体AMPS为起始原料,在水溶液中低温氧化还原体系为引发剂,合成了一种新型的酸性糊化剂。分析了影响聚合反应的各种因素,确定了最佳聚合条件,评价了胶凝酸的基本性能,研究了胶凝酸的作用机理。结果表明:ZCY-1具有良好的增粘、耐高温和缓酸岩反应性能,当ZCY-1质量分数为1%时,20%质量分数的酸化液在150℃高温下粘度可达37.5 mPa·s,剪切速率为170s-1;与石灰石反应60 min后胶凝酸的质量分数仍为11.9%,是普通酸的7倍,可满足高温井酸化的需要。
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