Hole Burning in the IR Predissociation Spectrum of SF6-dimers

Laser Chemistry Pub Date : 1900-01-01 DOI:10.1155/LC.8.275
B. Heijmen, C. Liedenbaum, S. Stolte, J. Reuss
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引用次数: 4

Abstract

Hole burning experiments with two CO2 lasers have been performed to obtain insight in the predissociation mechanism of SF6-dimers. For the well known double peak predissociation spectrum, always two correlated holes are observed. Strongly enhanced widths of the holes are found for dimers with higher internal energy.
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sf6 -二聚体红外预解光谱中的烧孔现象
为了深入了解sf6 -二聚体的预解离机理,采用两种CO2激光器进行了孔燃烧实验。对于众所周知的双峰预解谱,总是观察到两个相关的空穴。发现具有较高内能的二聚体的孔洞宽度明显增大。
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