Study on Biomimetic Antifouling Surface Preparation based on Surface Microstructure of Crabs

Zongcheng Yang, Xiuqin Bai, Xiaoyan He, C. Yuan
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Abstract

Biofouling is an extensively studied problem that results in significant economic and environmental loss. Underwater structures such as ships and pipelines will be subjected to the settlement of marine fouling organisms and then suffer from ship fouling after immersed in seawater. Some marine lives maintain their surface cleanliness through the micro structure of their own epidermis, which provides an important inspiration for the construction of microstructure antifouling coatings. In this study, Swimming crab is chosen as the main research object. The surface microstructures of this carb are investigated and measured by digital microscope and scanning electron microscope, which shows a composite scale microstructure on the surface of crabs. Cylinder-based microstructures with different spaces of $4 \mu \mathrm{m}$ and $7 \mu \mathrm{m}$ were formed on silicon wafers through reactive ion etching (RIE), according to actual tests for crabs' surface topography parameters. The antifouling tests of microstructures samples are conducted using phaeodactylum tricornutum. The results show that the microstructures with spaces of $4 \mu \mathrm{m}$ and $7 \mu \mathrm{m}$ has a good antifouling/fouling release performance. Proper design of biomimetic microstructure has a great contribution to antifouling surface.
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基于螃蟹表面微结构的仿生防污表面制备研究
生物污染是一个被广泛研究的问题,它会造成重大的经济和环境损失。船舶、管道等水下构筑物浸泡在海水中后,会受到海洋污染生物的沉降,进而发生船舶污染。一些海洋生物通过自身表皮的微观结构来保持其表面的清洁度,这为微结构防污涂层的构建提供了重要的启示。本研究以梭子蟹为主要研究对象。利用数码显微镜和扫描电镜对碳水化合物的表面微观结构进行了研究和测量,发现螃蟹表面呈复合尺度微观结构。采用反应离子刻蚀法(RIE)在硅片上形成了不同空间$4 \mu \ mathm {m}$和$7 \mu \ mathm {m}$的圆柱形微结构。用三角褐指藻对微结构样品进行了防污试验。结果表明,$4 \mu \mathrm{m}$和$7 \mu \mathrm{m}$空间的微结构具有良好的防污/结垢释放性能。仿生微结构的合理设计对表面防污有很大的贡献。
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