Uni-Leg Thermoelectric Module Comprised by Coated Hybrid-Perovskite Thin Film

S. Saini, A. Baranwal, T. Yabuki, S. Hayase, K. Miyazaki
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Abstract

Thermoelectric materials can convert thermal energy into electrical energy without any moving part which leads its path of application to the era of printed and flexible electronics. CsSnI3 perovskite can be a promising thermoelectric material for the next-generation energy conversion due to its intrinsic ultra-low thermal conductivity and large Seebeck coefficient but enhancement of electrical conductivity is still required. CsSnI3 can be prepared by wet process which can reduce the cost of flexible thermoelectric module. In this work, CsSnI3 thin films were fabricated by spin coating wet process. Thin films were structurally and chemically characterized using XRD and SEM. Thermoelectric properties such as electrical conductivity, Seebeck coefficient, and thermal conductivity were measured at 300 K. Uni-leg thermoelectric modules were fabricated on a glass substrate using CsSnI3 thin films. The maximum output is about 0.8 nW for 5 legs (25 mm × 3 mm × 600 nm) modules for the temperature difference of about 5°C. These results will open a new pathway to thermoelectric modules for flexible electronics in spite of low output power.
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由涂覆混合钙钛矿薄膜组成的单腿热电模块
热电材料无需任何运动部件即可将热能转化为电能,从而将其应用于印刷和柔性电子时代。CsSnI3钙钛矿由于其固有的超低导热系数和大塞贝克系数,可以成为下一代能量转换的热电材料,但其导电性仍有待提高。采用湿法制备CsSnI3可以降低柔性热电模块的成本。本文采用自旋镀膜湿法制备了CsSnI3薄膜。利用XRD和SEM对薄膜进行了结构和化学表征。在300 K时测量热电性能,如电导率、塞贝克系数和导热系数。采用CsSnI3薄膜在玻璃基板上制备了单腿热电模块。5个支腿模块(25mm × 3mm × 600nm)在5℃左右的温差下,最大输出功率约为0.8 nW。尽管输出功率低,但这些结果将为柔性电子器件的热电模块开辟一条新的途径。
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