{"title":"Synthesis and Thermoelectric Properties of (Sr,Yb)yCo4Sb12 Double Filled Skutterudites","authors":"S. Bai, X.Y. Zhao, Y. Pei, L.D. Chen, W.Q. Zhang","doi":"10.1109/ICT.2006.331301","DOIUrl":null,"url":null,"abstract":"(Sr,Yb)<sub>y</sub>Co<sub>4</sub>Sb<sub>12</sub> double filled skutterudites are synthesized by a melting method and sintered by Spark Plasma Sintering (SPS) technique. Small amount of Yb<sub>2</sub>O<sub>3 </sub> and YbSb<sub>2</sub> as impurity phases are found with high ytterbium content in the X-ray diffraction patterns of sintered materials. The thermal conductivity, electrical conductivity and Seebeck coefficient are measured from room temperature to 850 K. The influence of different filling fractions of ytterbium on the thermoelectric properties of (Sr,Yb)<sub>y</sub>Co<sub>4</sub>Sb<sub>12</sub> is studied. The lattice thermal conductivity of double filled skutterudites is reduced dramatically as compared to that of Sr single-filled skutterudites with similar filling fractions. An enhancement in power factor and dimensionless thermoelectric figure of merit (ZT) is observed in the double filled skutterudites","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"56 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"2006 25th International Conference on Thermoelectrics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ICT.2006.331301","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 5
Abstract
(Sr,Yb)yCo4Sb12 double filled skutterudites are synthesized by a melting method and sintered by Spark Plasma Sintering (SPS) technique. Small amount of Yb2O3 and YbSb2 as impurity phases are found with high ytterbium content in the X-ray diffraction patterns of sintered materials. The thermal conductivity, electrical conductivity and Seebeck coefficient are measured from room temperature to 850 K. The influence of different filling fractions of ytterbium on the thermoelectric properties of (Sr,Yb)yCo4Sb12 is studied. The lattice thermal conductivity of double filled skutterudites is reduced dramatically as compared to that of Sr single-filled skutterudites with similar filling fractions. An enhancement in power factor and dimensionless thermoelectric figure of merit (ZT) is observed in the double filled skutterudites
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