Stress-Corrosion Cracking of a Brass Radiator Coil

P. Ogden
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Abstract

An interstage radiator gas coil began leaking after only 45 days of service. The original brass coil with several aluminum fins was replaced three times but each replacement lasted less than a day. After removing the fins, leaks were found at circumferential cracks. A section of a tube was removed and split, revealing a series of cracks, evenly spaced. Crack spacing coincided with fin spacing, indicating that stresses incurred during installation of the fins promoted failure. Metallographic examination showed intergranular, branched cracking, characteristic of stress corrosion failures, with the cracks starting on the inside surfaces of the tubes. There was no known corrosive agent in the system, and no other corrosion damage could be found. Qualitative tests and spectrographic analysis gave a positive indication for mercury. The spacing of the cracks, the branched intergranular cracking, the rapid failure, and presence of mercury led to the conclusion of stress-corrosion cracking. It was impossible to remove mercury from the system so carbon steel coils were substituted for the brass ones. The carbon steel coils gave failure-free service for over nine years.
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黄铜散热器盘管的应力腐蚀开裂
一个级间散热器气体盘管在使用45天后开始泄漏。原来的带有几个铝鳍的黄铜线圈被更换了三次,但每次更换的时间都不到一天。拆下翅片后,在周向裂缝处发现了泄漏。一根管子的一部分被取出并切开,露出了一系列均匀间隔的裂缝。裂缝间距与肋片间距一致,说明肋片安装过程中产生的应力促进了破坏。金相检查显示,裂纹沿晶,分支开裂,具有应力腐蚀失效的特征,裂纹开始于管的内表面。系统中未发现已知的腐蚀剂,也未发现其他腐蚀损伤。定性试验和光谱分析证实了汞的存在。裂纹的间距、分支晶间裂纹、快速破坏和汞的存在导致应力腐蚀裂纹的结论。从系统中去除汞是不可能的,所以碳钢线圈代替了黄铜线圈。碳钢盘管提供了超过9年的无故障服务。
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