Maleik Anhidrit/Stiren Kopolimerinin Bazı Primer Alkol Türevlerinin Sentezi ve Termomekanik Analizi

Ersen Yilmaz
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Abstract

In this study, Maleic anhydride/Styrene (MAS) copolymer was synthesized. The synthesized copolymer was characterized and then modified with two different primary alcohols (propyl and butyl). Dissolution, FT-IR and thermo-mechanical (TMA) analyzes of the copolymer and its two modified ester derivatives were performed. The ester numbers of the obtained derivatives were calculated. Although the ester derivatives showed dissolution behavior in the same solvents as the MAS copolymer, they dissolved faster. Modification was confirmed in the FT-IR spectra. It was also found that the derivatives were more elastic than the MAS copolymer and had a lower glass transition temperatures. The calculated ester numbers were also close to each other.
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本研究合成了马来酸酐/苯乙烯(MAS)共聚物。对合成的共聚物进行了表征,然后用两种不同的伯醇(丙基和丁基)进行了改性。对该共聚物及其两种改性酯衍生物进行了溶解、红外光谱(FT-IR)和热力学(TMA)分析。计算了所得衍生物的酯数。尽管酯衍生物在与MAS共聚物相同的溶剂中表现出溶解行为,但它们溶解得更快。在FT-IR光谱中证实了修饰。还发现衍生物比MAS共聚物具有更大的弹性和更低的玻璃化转变温度。计算得到的酯数也很接近。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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