The effect of recasting on microstructure of dental ceramic alloys

Wang Yinghui, Qiu Fen-fang, P. Yu, Wu Wei-qing, Cheng Hui
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Abstract

PURPOSE To investigate the effects of recasting on metallographic microstructure of cobalt-chromium(Co-Cr), commercially pure titanium(cpTi), palladium-copper-gallium(Pd-Cu-Ga), aurum-platinum(Au-Pt) ceramic alloys. METHODS Without adding new alloys, Co-Cr, cpTi, Pd-Cu-Ga and Au-Pt ceramic alloys were recasted for 1-3 times under the circumstance of vacuum compressive casting with argon. Before each recasting, these 4 ceramic alloys casted previously were treated by the most appropriate way which has been reported by our previous study. According to GB/T13298-2015 standards, the specimens of 4 ceramic alloys after recasting 1-3 times were grinded, polished, and etched and then the metallographic microstructure of them were determined by a metallographic microscope or scanning electron microscopy(SEM). RESULTS With the increase of recasting times, the microstructure of Co-Cr ceramic alloy showed grain growth, grain matrix increase, and the intermetallic compound in the grain boundary increase, the microstructure of the cpTi ceramic alloy showed grain growth. The samples of cpTi ceramic alloy recasting twice appeared shaft tendency, and the ones which were recasted 3 times were compound of α-phase and β-phase. The microstructure of the Pd-Cu-Ga ceramic alloy showed grain growth slightly after casting 2-3 times, while no significant change was found on the microstructure of the Au-Pt ceramic alloy. CONCLUSIONS Recasting changes the microstructure of Co-Cr, cpTi, and Pd-Cu-Ga ceramic alloys, and the ceramic alloys may recycled by the manufacturers.
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重铸对牙科陶瓷合金显微组织的影响
目的研究重铸对钴铬(Co-Cr)、市纯钛(cpTi)、钯铜镓(Pd-Cu-Ga)、金铂(Au-Pt)陶瓷合金金相组织的影响。方法在不添加新合金的情况下,对Co-Cr、cpTi、Pd-Cu-Ga和Au-Pt陶瓷合金在氩气真空压缩铸造条件下进行1 ~ 3次重铸。在每次重铸之前,这4种陶瓷合金都经过了最合适的处理,这在我们之前的研究中已经报道过。按照GB/T13298-2015标准,对重铸1-3次后的4种陶瓷合金试样进行研磨、抛光、蚀刻,然后用金相显微镜或扫描电镜(SEM)对其金相组织进行测定。结果随着重铸次数的增加,Co-Cr陶瓷合金的显微组织表现为晶粒长大,晶粒基体增加,晶界内金属间化合物增多,cpTi陶瓷合金的显微组织表现为晶粒长大。2次重铸的cpTi陶瓷合金试样呈轴状,3次重铸的样品为α-相和β相的复合。浇注2 ~ 3次后,Pd-Cu-Ga陶瓷合金的显微组织略有晶粒长大,而Au-Pt陶瓷合金的显微组织无明显变化。结论重铸可改变Co-Cr、cpTi和Pd-Cu-Ga陶瓷合金的显微组织,陶瓷合金可由生产企业回收利用。
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