Thermal Shock Ageing of Joints Soldered Using Formic Acid Vapors on Thick Printed Copper Substrates

M. Hirman, D. Michal, J. Řeboun, F. Steiner
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Abstract

This article addresses the soldering of larger components onto ceramic substrates with printed copper patterns with a reduced amount of flux. The main aim of the research was to find a suitable soldering method and study the reliability of soldered joints on ceramic substrates under thermal shock ageing. The mock-up chips were used in the test and for this reason the test was primarily focused on bottom joint in the structure or sandwich structures. In the experiment, vacuum soldering using formic acid vapors to reduce oxides was used. Then the samples were observed under X-RAY radiation and submitted for thermal shock testing (-40 °C / 125° C / 1000 cycles). After the shock testing, another X-RAY scan with void area measurement and shear strength testing were realized. The results showed that our contacting soldering process on ceramic substrates is applicable and the samples also endures the shock ageing, especially bottom joint between ceramic substrate with Cu layer and solder alloy. The results also showed that void area and mechanical shear strength of soldered ceramic samples are relatively comparable with standard samples (FR-4).
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用甲酸蒸气在厚印刷铜基板上焊接接头的热冲击老化
本文讨论了在陶瓷基板上焊接较大的元件,并使用减少的助焊剂印刷铜图案。研究的主要目的是寻找一种合适的焊接方法,并研究陶瓷基板上焊接接头在热冲击老化下的可靠性。在测试中使用了模拟芯片,因此测试主要集中在结构或夹层结构的底部关节上。在实验中,使用甲酸蒸气来减少氧化物的真空焊接。然后在x射线辐射下观察样品,并提交热冲击测试(-40°C / 125°C / 1000次循环)。冲击试验结束后,再进行x射线扫描,测量空隙面积并进行抗剪强度测试。结果表明,陶瓷基板接触焊接工艺是可行的,试样具有良好的抗冲击老化性能,特别是含Cu层陶瓷基板与钎料合金的底部接头。结果还表明,焊接陶瓷样品的空洞面积和机械抗剪强度与标准样品(FR-4)相对相当。
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