{"title":"Designing proteins to transfer electrons","authors":"J. Regan, J. Onuchic","doi":"10.1109/IEMBS.1993.979267","DOIUrl":null,"url":null,"abstract":"The ability to design electron transfer (ET) proteins that can emulate the properties of biological systems will help to answer questions in biology, but should also help to answer questions in the areas of energy conversion, catalysis, and molecular electronics. A quantum mechanical model is presented for ET reactions, which both successfully predicts relative ET rates, and suggests a simple design paradigm for developing artificial molecules capable of ET.","PeriodicalId":408657,"journal":{"name":"Proceedings of the 15th Annual International Conference of the IEEE Engineering in Medicine and Biology Societ","volume":"51 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1993-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of the 15th Annual International Conference of the IEEE Engineering in Medicine and Biology Societ","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/IEMBS.1993.979267","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract

The ability to design electron transfer (ET) proteins that can emulate the properties of biological systems will help to answer questions in biology, but should also help to answer questions in the areas of energy conversion, catalysis, and molecular electronics. A quantum mechanical model is presented for ET reactions, which both successfully predicts relative ET rates, and suggests a simple design paradigm for developing artificial molecules capable of ET.
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设计蛋白质来传递电子
设计能够模拟生物系统特性的电子转移(ET)蛋白的能力将有助于回答生物学中的问题,但也应该有助于回答能量转换、催化和分子电子学领域的问题。提出了ET反应的量子力学模型,该模型成功地预测了相对ET速率,并为开发具有ET能力的人工分子提供了一个简单的设计范例。
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