MOVPE-preparation of Si(111) surfaces for III–V nanowire growth

M. Steidl, A. Paszuk, Weihong Zhao, S. Bruckner, A. Dobrich, O. Supplie, Johannes Luczak, P. Kleinschmidt, H. Doscher, T. Hannappel
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Abstract

We studied the preparation of the clean Si(111) surface in H2 ambient with in situ reflection anisotropy spectroscopy and UHV-based surface science tools after contamination-free transfer. X-ray photoelectron spectroscopy confirmed complete oxide removal after high-temperature annealing. In situ RAS enabled observation of the oxide removal in dependence of process temperature. Monohydride termination was verified by Fourier transform infrared spectroscopy which agrees with a (1×1) surface reconstruction we observed by scanning tunneling microscopy and low energy electron diffraction. By atomic force microscopy analysis of the morphology, we found that wet-chemical pretreatment has an impact on the different silicon surfaces we have prepared, including homoepitaxy and termination of silicon with arsenic.
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用于III-V纳米线生长的Si(111)表面的movpe制备
利用原位反射各向异性光谱和基于uhv的表面科学工具,研究了无污染转移后在H2环境下制备干净的Si(111)表面。x射线光电子能谱证实高温退火后氧化物完全去除。原位RAS可以观察到氧化去除与工艺温度的关系。傅里叶变换红外光谱证实了一氢化物的终止,这与扫描隧道显微镜和低能电子衍射观察到的(1×1)表面重建一致。通过原子力显微镜的形貌分析,我们发现湿化学预处理对我们制备的不同硅表面有影响,包括同外延和硅与砷的终止。
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