Synthesis and structure of monoclinic bismuth vanadate doped with molybdenum

K. Bychkov, K. Terebilenko, V. Baumer, N. Slobodyanik
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Abstract

The synthetic conditions of BiVO4:Mo crystallization in the molten salts of K-Bi-V-Mo-O have been studied. The compound crystallizes in the monoclinic system, space group I2/a, with unit cell parameters a = 5.1153(3), b = 11.7012(1), c = 5.1878(1) Å, β = 90.24(1)°, Z = 4 representing scheelite-related structure. The formula of the compound established to be Bi0.98V0.95Mo0.05O4.
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掺钼单斜钒酸铋的合成与结构
研究了在K-Bi-V-Mo-O熔盐中合成BiVO4:Mo结晶的条件。该化合物在空间群I2/a单斜晶系中结晶,晶胞参数a = 5.1153(3), b = 11.7012(1), c = 5.1878(1) Å, β = 90.24(1)°,Z = 4代表白钨矿相关结构。化合物的分子式为bi0.98 v0.95 mo0.050 o4。
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