Development of Particles Dispersion Type Sprayed Coatings with Water-Repellency and Photo-Catalytic Activity

M. Futamata, H. Itoh, K. Nakanishi, N. Kuramoto, Y. Kamoshita, A. Shindoh, Michio Saitoh, Mitsuaki Yamada
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Abstract

The sprayed coating containing fl uorine-carbon showed high water repellency (the contact angle for water droplet was 145°). However, the water repellency of the sprayed coating decreased with adsorption of organic materials, NOx, and SOx, which discharged from the automobile. To remove the adsorption compounds from the coating surface, we decide to add titanium oxide (TiO2) in the coating, which could be able to oxidize the surface adsorption compounds photo-catalytically. It was found that the particles dispersion type sprayed coatings prepared by fl ame spray technique using aluminum tubing fi lling with fl uorine-carbon (15.2mass%) and titanium oxide (0.5mass%) had high photo-catalytic activity for liquid phase decomposition of methylene blue without decreasing waterrepellency.
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具有防水性和光催化活性的颗粒分散型喷涂涂料的研制
含氟碳涂层具有较高的拒水性(水滴接触角为145°)。然而,随着汽车排放的有机物质、氮氧化物和硫氧化物的吸附,喷涂涂层的拒水性下降。为了去除涂层表面的吸附化合物,我们决定在涂层中加入氧化钛(TiO2),它可以光催化氧化表面吸附化合物。结果表明,用铝管填充氟碳(15.2质量%)和氧化钛(0.5质量%),采用火焰喷涂技术制备的颗粒分散型喷涂涂料对亚甲基蓝液相分解具有较高的光催化活性,且不降低其防水性。
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