Heavy Metals Adsorption on Cyanex-272 Modified Activated Carbon: Efficacy and Selectivity

Zeinab Ezzeddine, Layla Abdallah, Hussein Hamad
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引用次数: 1

Abstract

This study investigated the potential use of activated carbon functionalized with Cyanex272 (AC-Cyanex 272), in the removal of lead, copper and zinc cations from aqueous solutions. The modified adsorbent was characterized by powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, Zeta-Meter and particle size distribution. Batch adsorption experiments were performed as a function of pH, contact time, and initial metal ion concentration. Adsorption was found dependent on these parameters. The adsorption capacities were very high (126.36, 175.5 and 157.16 mg g-1 for Pb2+, Cu2+ and Zn2+ respectively). Langmuir and Freundlich isotherms were used as models for the equilibrium adsorption data and adsorption kinetic data are best described by the second order model.
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改性活性炭对重金属的吸附效果及选择性研究
本研究探讨了氰化272 (ac - Cyanex272)功能化活性炭在去除水溶液中铅、铜和锌阳离子方面的潜在用途。采用粉末x射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、Zeta-Meter和粒度分布对改性吸附剂进行了表征。通过pH值、接触时间和初始金属离子浓度的变化,进行了批量吸附实验。吸附作用与这些参数有关。对Pb2+、Cu2+和Zn2+的吸附量分别为126.36、175.5和157.16 mg g-1。平衡吸附数据采用Langmuir等温线和Freundlich等温线模型,吸附动力学数据最好用二级模型来描述。
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