Synthesis and Optical Characterization of Carbon Dot from Peels of Dragon Fruit and Pear

S. Hepriyadi, Isnaeni
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引用次数: 4

Abstract

Fluorescence materials such as carbon dots are unique and non-toxic materials that can be produced using many methods. In this research, synthesis and optical characterization of carbon dots from the peels of dragon fruit and pear have been done. The synthesis uses bottom-up method using microwave with 20 minutes, 40 minutes, and 80 minutes of heating time. The result of optical characterizations showed that the samples that have been heat treated are carbon dots based of the absorbance in the range of 280-350 nm, and the intensity are decreased in the range of visible and infrared wavelength. There are emission and intensity changes by different heat treatments. From the samples of dragon fruit's peels, the emission wavelength tended to shift toward visible light at the wavelength of 551.51 nm, 507.98 nm and 487.28 nm with the excitation at the wavelength of 420 nm from pulsed pico-laser. While, the emission wavelength from the samples of pears peels were fluctuate in wavelength of 529.09 nm, 507.52 nm and 519.46 nm. Similarly, the time-resolved photoluminescence characterization test showed that there were time changes in each sample of carbon dot. The decay lifetime of carbon dots was fluctuated between 4.5 ns - 5.4 ns for dragon fruit’s peels and about 1.9 ns - 2.4 ns for pear's peels.
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火龙果和梨果皮碳点的合成及光学表征
碳点等荧光材料是一种独特的无毒材料,可以通过多种方法生产。本研究对火龙果和梨果皮碳点进行了合成和光学表征。合成采用微波自底向上法,加热时间分别为20分钟、40分钟、80分钟。光学表征结果表明,热处理后的样品在280 ~ 350 nm范围内吸光度为碳点,在可见光和红外波长范围内强度减小。不同的热处理方式会产生辐射和强度的变化。火龙果果皮样品在脉冲激光激发波长为420 nm时,发射波长在551.51 nm、507.98 nm和487.28 nm处有向可见光方向偏移的趋势。梨皮样品的发射波长在529.09 nm、507.52 nm和519.46 nm上下波动。同样,时间分辨光致发光表征测试表明,每个碳点样品都有时间变化。火龙果果皮的碳点衰变寿命在4.5 ~ 5.4 ns之间波动,梨果皮的碳点衰变寿命在1.9 ~ 2.4 ns之间波动。
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