Metal Oxide Coating On Biodegradable Magnesium Alloys

Pralhad Pesode, Shivprakash B. Barve, Sagar V. Wankhede, Amar Chipade
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引用次数: 4

Abstract

Magnesium is a biodegradable metal that has potential in orthopaedics. It has several advantages over other metallic materials because it is biocompatible and degradable now being used for biomedical applications, including elimination of stress shielding effects, enhancing degradation properties and enhancing biocompatibility concern in vivo, eliminating the second surgery for implant removal. Bioabsorbable magnesium (Mg) and related alloys have been limited in their usage because of its lower corrosion resistance. Surface alteration and functionality, in addition to basic alloying, is an important technique to deal with Mg and its alloys' reduced corrosion resistance. Magnesium's rapid depreciation however is a double-edged sword because it's critical to match bone renewal to material corrosion. As a result, calcium phosphate coatings have been proposed as a way to slow down corrosion. There are various possible calcium phosphate phases and their coating methods and can give a few distinct properties to various applications. Despite magnesium's lower melting point and greater reactivity, calcium phosphate coatings require precise settings to be effective. Because of their toxicity, non-biodegradability, and much higher cost, the recently used inorganic conversion coatings are less appealing and their application is limited. Conversion coatings are a viable alternative technology that is based on a cost- effective, environmentally friendly, and biodegradable organic component. Surface chelating functional groups in these compounds allow them to link with the magnesium/surface hydroxide layer while also providing anchoring groups for the polymer topcoat. Nanoreservoirs with multilayer inhibitors for active self-healing corrosion resistance thrive in this environment. This study examines the organic conversion coatings for Mg and its alloys in depth.
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可生物降解镁合金的金属氧化物涂层
镁是一种可生物降解的金属,在骨科方面有很大的潜力。与其他金属材料相比,它具有生物相容性和可降解性,现在被用于生物医学应用,包括消除应力屏蔽效应,增强降解性能和增强体内生物相容性,消除植入物移除的第二次手术。生物可吸收镁(Mg)及其合金的耐腐蚀性较低,限制了其应用。除基本合金化外,表面蚀变和功能化是解决镁及其合金耐蚀性降低的重要技术。然而,镁的快速贬值是一把双刃剑,因为骨骼更新与材料腐蚀相匹配至关重要。因此,磷酸钙涂层被提出作为一种减缓腐蚀的方法。有各种可能的磷酸钙相和它们的涂层方法,并且可以为各种应用提供一些不同的性能。尽管镁的熔点较低,反应性更强,但磷酸钙涂层需要精确的设置才能有效。由于无机转化涂料的毒性、不可生物降解性和较高的成本,近年来使用的无机转化涂料吸引力较低,其应用受到限制。转化涂料是一种可行的替代技术,基于成本效益,环境友好,可生物降解的有机成分。这些化合物中的表面螯合官能团允许它们与镁/表面氢氧化物层连接,同时也为聚合物面漆提供锚定基团。具有多层自愈抗腐蚀抑制剂的纳米油藏在这种环境中茁壮成长。本文对镁及其合金的有机转化涂层进行了深入的研究。
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