HEAVY METALS QUANTIFICATION AND CORRELATIVE CARCINOGENIC-RISKS EVALUATION IN SELECTED ENERGY DRINKS SOLD IN BAYELSA STATE USING ATOMIC ABSORPTION SPECTROSCOPIC TECHNIQUE

SAMUEL J. BUNU, DORATHY GEORGE, DEGHINMOTEI ALFRED-UGBENBO, BENJAMIN U. EBESHI
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Abstract

Objective: The study aimed to quantify the concentrations and carcinogenic-related health risks assessment of some heavy metals in selected energy drinks frequently utilized in Bayelsa State, Nigeria. Methods: Eleven energy drinks samples were purchased from the general markets in Amassoma and Yenagoa, Bayelsa State, Nigeria, and were labeled D1–D11. The samples were digested using 10 ml of nitric acid at 120-150 ℃, and 2 ml of Perchloric acid was added after attaining room temperature, it was digested further until a clear solution was obtained, then made up to 25 ml with distilled water. The concentration of lead, cadmium, iron, and zinc were determined and quantified using Atomic Absorption Spectrophotometry (AAS), and the health-associated risks of these metals were evaluated using the standard Target Health Quotient (THQ). Results: The EDI (Estimated Daily Intake) of lead (Pd), Cadmium (Cd), iron (Fe), and zinc (Zn) was 0.130, 0.001, 0.726, and 0.193 mg/l, respectively, all were within the World Health Organization (WHO)-acceptable range. The Chronic Daily Intake (CDI) of Pd, Cd, Fe, and Zn was obtained as 0.001 to 0.010, 5.7 x 10-5, 0.001 to 0.050, and 0.0001 to 0.010 mg/l respectively. Conclusion: THQ for all metals analyzed was<1, the WHO acceptable limit. All the heavy metals were within acceptable THQ limits, thus posing no carcinogenic health potential risks on long-term consumption.
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巴伐利亚州部分功能饮料中重金属含量的原子吸收光谱分析及相关致癌风险评价
目的:本研究旨在量化尼日利亚巴耶尔萨州经常使用的某些功能饮料中某些重金属的浓度和致癌相关健康风险评估。方法:从尼日利亚巴耶尔萨州的Amassoma和Yenagoa普通市场购买11种功能饮料样品,标记为D1-D11。样品在120-150℃条件下用10ml硝酸消化,达到室温后加入2ml高氯酸,进一步消化至澄清溶液,再用蒸馏水配制至25ml。使用原子吸收分光光度法(AAS)测定和定量铅、镉、铁和锌的浓度,并使用标准目标健康商(THQ)评估这些金属的健康相关风险。结果:铅(Pd)、镉(Cd)、铁(Fe)和锌(Zn)的EDI分别为0.130、0.001、0.726和0.193 mg/l,均在世界卫生组织(WHO)可接受范围内。Pd、Cd、Fe和Zn的慢性日摄入量(CDI)分别为0.001 ~ 0.010、5.7 × 10-5、0.001 ~ 0.050和0.0001 ~ 0.010 mg/l。结论:所分析金属的THQ值均为WHO可接受限度1。所有重金属均在可接受的四氢量范围内,因此长期食用不会对健康构成致癌潜在风险。
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