Research of Nano-modified Plain Cement Concrete Mixtures and Cement-Based Concrete

IF 3.6 3区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY International Journal of Concrete Structures and Materials Pub Date : 2023-09-18 DOI:10.1186/s40069-023-00601-8
Shilin Yang, Andrii Bieliatynskyi, Viacheslav Trachevskyi, Meiyu Shao, Mingyang Ta
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Abstract

Abstract The use of complex modifiers for plain cement concrete mixtures and concrete is becoming increasingly popular in modern materials science. The article presents studies of the influence of a polymer additive structured by carbon nanomaterials on physical and mechanical characteristics of plain cement concrete mixtures. IR spectroscopy and thermogravimetry have shown that the use of carbon nanomaterials significantly altered the structure of plain cement concrete mixtures. As a result of the fact that the high-strength nanomaterial is the center of crystallization of cement rock newly formed structures, a denser reinforced microstructure is formed, which significantly increases the strength properties of plain cement concrete mixtures. The inclusion of a polymer complex additive in plain cement concrete mixtures leads to higher and longer plasticizing, which plays an important role in the production of monolithic products. It was determined that, in the presence of a complex modifier (polymer additive structured by carbon nanotubes), the crystalline structure of calcium hydrosilicates is compacted, which causes high physical and mechanical characteristics of modified plain cement concrete mixtures. It has been experimentally shown that the additive Ethacryl HF (France) from the class of polycarboxylates, chosen for research, acts as an accelerator for setting and curing cement paste, and also increases its strength characteristics. In general, in this study, there is a water-reducing effect from the application of the additive for all plain cement concrete mixtures. Water requirements are reduced by 5 mas. %, while the strength is increased by 19%. The formulation of plain cement concrete mixtures modified by polymer additives, structured by carbon nanotubes, with high performance were developed.

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纳米改性素水泥混凝土混合料及水泥基混凝土的研究
在现代材料科学中,使用复合改性剂对素水泥混凝土混合料和混凝土进行改性是越来越受欢迎的研究方向。本文研究了碳纳米结构聚合物添加剂对普通水泥混凝土混合料物理力学特性的影响。红外光谱和热重分析表明,碳纳米材料的使用显著改变了普通水泥混凝土混合物的结构。由于高强纳米材料是水泥岩石新形成结构的结晶中心,形成了更致密的增强微观结构,从而显著提高了素水泥混凝土混合料的强度性能。在普通水泥混凝土混合料中掺入聚合物络合添加剂,可以提高混凝土的塑化程度,延长混凝土的塑化时间,这对整体产品的生产具有重要作用。结果表明,在复合改性剂(由碳纳米管构成的聚合物添加剂)的存在下,氢硅酸钙的晶体结构被压实,从而导致改性的普通水泥混凝土混合物具有较高的物理和机械特性。实验表明,研究选用的聚羧酸酯类添加剂HF乙稀(法国)对水泥浆体的固化和养护起到了促进剂的作用,并提高了水泥浆体的强度特性。总的来说,在本研究中,添加剂的应用对所有素水泥混凝土混合物都有减水效果。需水量减少5毫克。%,强度提高19%。研制了以碳纳米管为结构的聚合物改性素水泥混凝土混合料的高性能配方。
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来源期刊
International Journal of Concrete Structures and Materials
International Journal of Concrete Structures and Materials CONSTRUCTION & BUILDING TECHNOLOGY-ENGINEERING, CIVIL
CiteScore
6.30
自引率
5.90%
发文量
61
审稿时长
13 weeks
期刊介绍: The International Journal of Concrete Structures and Materials (IJCSM) provides a forum targeted for engineers and scientists around the globe to present and discuss various topics related to concrete, concrete structures and other applied materials incorporating cement cementitious binder, and polymer or fiber in conjunction with concrete. These forums give participants an opportunity to contribute their knowledge for the advancement of society. Topics include, but are not limited to, research results on Properties and performance of concrete and concrete structures Advanced and improved experimental techniques Latest modelling methods Possible improvement and enhancement of concrete properties Structural and microstructural characterization Concrete applications Fiber reinforced concrete technology Concrete waste management.
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