Vladimir Arion, Oleg Palamarciuc, Sergiu Shova, Ghenadie Novitchi, Peter Rapta
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引用次数: 0
Abstract
The main aims of this work were the synthesis and characterization of iron(III) complexes with with a ditopic ligand H2L consisting of a bis(salicylidene)isothiosemicarbazide moiety with a N2O2 binding site and a crown-ether (O6) moiety. A series of high-spin iron(III) complexes, i.e. [FeIIILClBa(CH3OH)(H2O)0.5(ZnCl4)] (1), [FeIIILCl] (2), [FeIIIL(N3)] (3) and [(FeIIIL)2O] (4), were synthesized. The complexes were characterized by mass spectrometry, IR and UV-vis spectroscopy, variable temperature (VT) magnetic susceptibility measurements, M?ssbauer spectroscopy, single crystal X-ray diffraction and cyclic voltammetry.
期刊介绍：
The Journal of the Serbian Chemical Society -JSCS (formerly Glasnik Hemijskog društva Beograd) publishes articles original papers that have not been published previously, from the fields of fundamental and applied chemistry:
Theoretical Chemistry, Organic Chemistry, Biochemistry and Biotechnology, Food Chemistry, Technology and Engineering, Inorganic Chemistry, Polymers, Analytical Chemistry, Physical Chemistry, Spectroscopy, Electrochemistry, Thermodynamics, Chemical Engineering, Textile Engineering, Materials, Ceramics, Metallurgy, Geochemistry, Environmental Chemistry, History of and Education in Chemistry.
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