Synthetic Element Chemistry based on Precise Designs of Reagents and Transition States

IF 0.2 4区 化学 Q4 CHEMISTRY, ORGANIC Journal of Synthetic Organic Chemistry Japan Pub Date : 2023-11-01 DOI:10.5059/yukigoseikyokaishi.81.1096
Keiichi Hirano, Masanobu Uchiyama
{"title":"Synthetic Element Chemistry based on Precise Designs of Reagents and Transition States","authors":"Keiichi Hirano, Masanobu Uchiyama","doi":"10.5059/yukigoseikyokaishi.81.1096","DOIUrl":null,"url":null,"abstract":"In recent years, the use of various elements has been attracting large attention in drug discovery and materials science. Particularly, organoborons and organosilicons are promising candidates owing to their high stability and relatively low toxicity. However, there are still limitations in the available chemical structures and hence development of novel skeletal-constructing methods is an urgent task in synthetic chemistry. Based on precise designs of boron and silicon ate complexes through an integration of theoretical and experimental chemistry, we have developed novel boration and silylation reactions.","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"121 6","pages":"0"},"PeriodicalIF":0.2000,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Synthetic Organic Chemistry Japan","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5059/yukigoseikyokaishi.81.1096","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0

Abstract

In recent years, the use of various elements has been attracting large attention in drug discovery and materials science. Particularly, organoborons and organosilicons are promising candidates owing to their high stability and relatively low toxicity. However, there are still limitations in the available chemical structures and hence development of novel skeletal-constructing methods is an urgent task in synthetic chemistry. Based on precise designs of boron and silicon ate complexes through an integration of theoretical and experimental chemistry, we have developed novel boration and silylation reactions.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
基于试剂和过渡态精确设计的合成元素化学
近年来,各种元素的使用在药物发现和材料科学中引起了很大的关注。特别是有机硼和有机硅,由于其高稳定性和相对较低的毒性,是有希望的候选人。然而,现有的化学结构仍然存在局限性,因此开发新的骨架构建方法是合成化学领域的一项紧迫任务。通过理论和实验化学的结合,精确设计了硼和硅盐配合物,我们开发了新的硼化和硅化反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
0.30
自引率
0.00%
发文量
120
审稿时长
6-12 weeks
期刊介绍: Information not localized
期刊最新文献
Synthetic Element Chemistry based on Precise Designs of Reagents and Transition States Use of Emerging C-H Functionalization Methods to Implement Strategies for the Divergent Total Syntheses of Bridged Polycyclic Natural Products Rapid Alternating Polarity as a Unique Tool for Synthetic Electrochemistry Synthesis of Structurally Diverse Polycyclic Arenes Using Tandem Oxidative Ring Expansion Strategy Divergent Transformation of Carboxylic Acids through Photocatalytic Decarboxylation with Hypervalent Iodine Reagents
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1