Recent Progress on Metallo-Supramolecular Polymers and the Electrochromic Devices Fabrication

IF 0.2 4区 化学 Q4 CHEMISTRY, ORGANIC Journal of Synthetic Organic Chemistry Japan Pub Date : 2023-11-01 DOI:10.5059/yukigoseikyokaishi.81.1089
Masayoshi Higuchi
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Abstract

This paper introduces our recent research on metallo-supramolecular polymers (MSPs) and the electrochromic (EC) device fabrication, including (1) control of metal sequence in one-dimensional (1D) MSPs, (2) design of two-dimensional (2D) MSPs, (3) three-dimensional (3D) hyperbranched MSPs, (4) EC devices (ECDs) with MSPs and (5) our trial for ECD applications. MSPs are a kind of coordination polymers and obtained by complexation of metal ions with multitopic organic ligands. MSPs show EC properties in the film state, activated by the electrochemical redox of the metal ions. The EC changes are caused by the reversible appearance and disappearance of the metal-to-ligand charge transfer (MLCT) absorption in the metal complex moieties of MSPs. ECDs with MSPs have great potential for the future’s smart window applications and spreading.
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金属超分子聚合物与电致变色器件制备研究进展
本文介绍了我们最近在金属超分子聚合物(MSPs)和电致变色(EC)器件制造方面的研究,包括:(1)一维(1D) MSPs中金属序列的控制,(2)二维(2D) MSPs的设计,(3)三维(3D)超支化MSPs,(4)带有MSPs的EC器件(ECDs)以及(5)我们在ECD应用方面的试验。MSPs是金属离子与多主题有机配体络合而成的一种配位聚合物。在金属离子的电化学氧化还原作用下,MSPs在薄膜状态下表现出EC特性。电导率的变化是由MSPs金属络合物中金属到配体电荷转移(MLCT)吸收的可逆出现和消失引起的。具有msp的ecd在未来的智能窗口应用和推广方面具有巨大的潜力。
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来源期刊
CiteScore
0.30
自引率
0.00%
发文量
120
审稿时长
6-12 weeks
期刊介绍: Information not localized
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