Determination of Chemical Explosive Remnants in Soils of Boko Haram’s Affected Areas of Gombe State Nigeria

Baba Adamu Mohammed, Oliver N. Maitera
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 Study Design and Place of Study: Samples for this research were collected from Bajoga, Nafada and Gombe metropolis and environs all in Funakaye, Nafada, and Gombe Local Government Areas respectively. Samples were taken only from places with recorded Boko Haram’s explosion activities. A control sample for each study area was taken from an area that has no record of Boko Haram attacks. Gombe State is located in the North-Eastern part of Nigeria on latitude10015’00’’N and longitude 11010’00’’E bordering Yobe, Borno, Adamawa, Taraba and Bauchi states.
 Methodology: The concentrations of explosive remnants (4-Nitrotoluene, 4-Propyl Benzaldehyde, 1,3-Dinitrotoluene, 2,4-Dinitrotoluene, 3,5- Dinitrotoluene, Trinitrotoluene, RDX and HMX) in the soil samples of the attacked areas were investigated using Gas Chromatography- Mass Spectrometer, GC-MS.
 Results: The result indicates 4-Nitrotoluene; 0.05-0.085µg/kg, 4-Propyl Benzaldehyde; 0.07-0.19µg/kg; 1,3-Dinitrotoluene; 0.005-0.060µg/kg, 2,4-DNT; 6.16-6.86µg/kg, 3,5-DNT; 0.40-0.90µg/kg, TNT; 0.29-0.66µg/kg and RDX and HMX were not detected. All the samples in the study area had 4-Nitrotolene and 4-Propyl Benzaldehyde concentrations above those in their respective controls. 1,3-DNT in Bajoga samples, 2,4-DNT in K Police station and K/mata, 3,5-DNT in Gombe metropolis, and TNT in NFD Police station were all found to be below the concentrations in their control
 Conclusion: There is possible 4-Nitrotolene and 4-Propyl Benzaldehyde contaminations in all the studied sites and absence of pollution by 1,3-DNT in Bajoga, 2,4-DNT in K Police station and K/mata, 3,5-DNT in Gombe metropolis, and TNT in NFD Police station.","PeriodicalId":8505,"journal":{"name":"Asian Journal of Chemical Sciences","volume":"2000 5","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Asian Journal of Chemical Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.9734/ajocs/2023/v13i6266","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract

Aim: This research was conducted to ascertain the level of pollution of our physical environment as a result of years of Boko Haram’s activities in Gombe State, North-Eastern Nigeria. Study Design and Place of Study: Samples for this research were collected from Bajoga, Nafada and Gombe metropolis and environs all in Funakaye, Nafada, and Gombe Local Government Areas respectively. Samples were taken only from places with recorded Boko Haram’s explosion activities. A control sample for each study area was taken from an area that has no record of Boko Haram attacks. Gombe State is located in the North-Eastern part of Nigeria on latitude10015’00’’N and longitude 11010’00’’E bordering Yobe, Borno, Adamawa, Taraba and Bauchi states. Methodology: The concentrations of explosive remnants (4-Nitrotoluene, 4-Propyl Benzaldehyde, 1,3-Dinitrotoluene, 2,4-Dinitrotoluene, 3,5- Dinitrotoluene, Trinitrotoluene, RDX and HMX) in the soil samples of the attacked areas were investigated using Gas Chromatography- Mass Spectrometer, GC-MS. Results: The result indicates 4-Nitrotoluene; 0.05-0.085µg/kg, 4-Propyl Benzaldehyde; 0.07-0.19µg/kg; 1,3-Dinitrotoluene; 0.005-0.060µg/kg, 2,4-DNT; 6.16-6.86µg/kg, 3,5-DNT; 0.40-0.90µg/kg, TNT; 0.29-0.66µg/kg and RDX and HMX were not detected. All the samples in the study area had 4-Nitrotolene and 4-Propyl Benzaldehyde concentrations above those in their respective controls. 1,3-DNT in Bajoga samples, 2,4-DNT in K Police station and K/mata, 3,5-DNT in Gombe metropolis, and TNT in NFD Police station were all found to be below the concentrations in their control Conclusion: There is possible 4-Nitrotolene and 4-Propyl Benzaldehyde contaminations in all the studied sites and absence of pollution by 1,3-DNT in Bajoga, 2,4-DNT in K Police station and K/mata, 3,5-DNT in Gombe metropolis, and TNT in NFD Police station.
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尼日利亚贡贝州博科圣地影响地区土壤中化学爆炸残留物的测定
目的:进行这项研究是为了确定由于博科圣地在尼日利亚东北部贡贝州多年的活动而对我们的物理环境造成的污染程度。研究设计和研究地点:本研究的样本分别来自富纳卡耶、纳法达和贡贝地方政府区的巴约加、纳法达和贡贝大都市及其周边地区。样本只取自有博科圣地爆炸活动记录的地方。每个研究区域的对照样本取自没有博科圣地袭击记录的地区。贡贝州位于尼日利亚东北部,北纬10015 ' 00 ",东经11010 ' 00 ",与约贝州、博尔诺州、阿达马瓦州、塔拉巴州和包奇州接壤。方法:爆炸物的浓度(3-Dinitrotoluene 4-Nitrotoluene 4-Propyl苯甲醛1,2,硝基甲苯,3,5 -二硝基甲苯、三硝基甲苯,RDX和HMX)袭击地区的土壤样品进行了使用气相色谱-质谱仪,气强生# x0D;结果:4-硝基甲苯;0.05-0.085µg/kg, 4-丙基苯甲醛;0.07 - -0.19µg / kg;1、3-Dinitrotoluene;0.005 - -0.060µg /公斤,2,4-DNT;6.16 - -6.86µg /公斤,3,5-DNT;0.40 - -0.90µg /公斤TNT炸药;0.29 ~ 0.66µg/kg, RDX、HMX未检出。研究区所有样品的4-硝基甲苯和4-丙基苯甲醛浓度均高于各自对照。巴约加区样品中1,3- dnt、K警察局和K/mata区样品中2,4- dnt、贡贝大都会区样品中3,5- dnt、NFD警察局样品中TNT的浓度均低于对照 结论:所有研究点均可能存在4-硝基甲苯和4-丙基苯甲醛污染,巴约加市未发现1,3-硝基甲苯污染,K派出所未发现2,4-硝基甲苯污染,贡贝市未发现K/mata、3,5-硝基甲苯污染,NFD派出所未发现TNT污染。
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