Enhanced Circular Dichroism of Z-Shaped Nanorod in Rectangular Nanohole Arrays

Ziye Zhang
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Abstract

Chiral nanostructures have attracted much attention due to the valuable applications in biochemistry, medicine industries, and photonic devices. In this study, we propose an ease-of-fabrication planar nanostructure that consists of rectangular nanohole arrays in which the Z-shaped nanorod is arranged. Theoretically, such chiral nanostructure supports significant absorption circular dichroism (CD) compared with the Z-shaped nanorod because charge distributions are tuned after the introduction of the rectangular frame. Meanwhile, the Z-shaped nanorod directs the flow of current on the rectangular frame, thereby generating the effective quadruple electron oscillation in the Z-shaped nanorod. A novel mode also emerges when an identical Z-shaped nanorod is added into the rectangular hole. The studies will provide a novel approach to enhance the CD effect of planar structures.
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矩形纳米孔阵列中z形纳米棒的圆二色性增强
手性纳米结构由于在生物化学、医药工业和光子器件等方面的重要应用而受到广泛关注。在这项研究中,我们提出了一种易于制造的平面纳米结构,该结构由矩形纳米孔阵列组成,其中排列着z形纳米棒。理论上,与z形纳米棒相比,这种手性纳米结构支持显著的吸收圆二色性(CD),因为在引入矩形框架后电荷分布被调整。同时,z形纳米棒引导电流在矩形框架上的流动,从而在z形纳米棒中产生有效的四重电子振荡。当在矩形孔中加入相同的z形纳米棒时,也会出现新的模式。该研究为提高平面结构的CD效应提供了一种新的途径。
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