Optical Properties of PVA Silicon Carbide Nano Composites Films Synthesized Via Laser Ablation

Hamid Shaker Mohsen, Hisham Mohammed Ali Hasan
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 Materials and Methods: Poly vinyl alcohol and silicon carbide's optical properties were examined. A pulsed laser with a 532 nm wavelength is used to create these nanoparticles into widespread nanoparticles in two environments (water and vinyl alcohol). Polyvinyl alcohol nanocomposite was created by spin coating silicon carbide particles with the weight fractions 0.90%, 0.91%, 0.93%, and 0.95%. Fourier spectroscopy was used to locate the functional groups based. Techniques FESEM were used to analyze the surface composition and nanoparticle dispersion on the membrane-surface of the nanocomposite. using spectroscopy UV-Vis used to record the absorbance spectrum in the range of (200-800) nm for ultraviolet radiation.
 Results: The direct energy gap (5.585, 5.310, 5.480, 4.986, 4.800) eV and the indirect (5.006, 4.880, 4.916, 4.683, 4.490) eV and Urbach energy (2.38, 2.45, 2.94, 2.74, 3.67) eV were calculated.for the samples by ratio, as shown in Table No. 1.
 Conclusion: By investigating the optical characteristics of nanoparticles, such as their extinction and absorption coefficients, direct and indirect optical energy gaps, and Urbach energies .increase in extinction and absorption coefficients Urbach energy when adding nano carbide to polyvinyl alcohol, results show narrowing of the direct and indirect energy gaps. This suggests that the nanocomposite's optical characteristics have improved.
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Abstract

Background: Enhancing the optical characteristics of nano-silicon carbide and polyvinyl alcohol films is thought to be crucial for obtaining the semiconductor with the lowest energy gap for applications in electrical devices, digital displays, and sensors. Materials and Methods: Poly vinyl alcohol and silicon carbide's optical properties were examined. A pulsed laser with a 532 nm wavelength is used to create these nanoparticles into widespread nanoparticles in two environments (water and vinyl alcohol). Polyvinyl alcohol nanocomposite was created by spin coating silicon carbide particles with the weight fractions 0.90%, 0.91%, 0.93%, and 0.95%. Fourier spectroscopy was used to locate the functional groups based. Techniques FESEM were used to analyze the surface composition and nanoparticle dispersion on the membrane-surface of the nanocomposite. using spectroscopy UV-Vis used to record the absorbance spectrum in the range of (200-800) nm for ultraviolet radiation. Results: The direct energy gap (5.585, 5.310, 5.480, 4.986, 4.800) eV and the indirect (5.006, 4.880, 4.916, 4.683, 4.490) eV and Urbach energy (2.38, 2.45, 2.94, 2.74, 3.67) eV were calculated.for the samples by ratio, as shown in Table No. 1. Conclusion: By investigating the optical characteristics of nanoparticles, such as their extinction and absorption coefficients, direct and indirect optical energy gaps, and Urbach energies .increase in extinction and absorption coefficients Urbach energy when adding nano carbide to polyvinyl alcohol, results show narrowing of the direct and indirect energy gaps. This suggests that the nanocomposite's optical characteristics have improved.
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激光烧蚀法合成PVA碳化硅纳米复合材料薄膜的光学性能
背景:增强纳米碳化硅和聚乙烯醇薄膜的光学特性被认为是获得在电子设备、数字显示器和传感器中应用的具有最低能隙的半导体的关键。 材料与方法:考察了聚乙烯醇和碳化硅的光学性能。使用波长为532纳米的脉冲激光将这些纳米颗粒在两种环境(水和乙烯醇)中形成广泛分布的纳米颗粒。分别以0.90%、0.91%、0.93%和0.95%的质量分数自旋包覆碳化硅颗粒制备聚乙烯醇纳米复合材料。采用傅立叶光谱法对其官能团进行定位。利用FESEM分析了纳米复合材料的表面组成和纳米颗粒在膜表面的分散情况。利用紫外-可见光谱法记录紫外辐射在(200-800)nm范围内的吸光度。 结果:计算出了直接能隙(5.585、5.310、5.480、4.986、4.800)eV和间接能隙(5.006、4.880、4.916、4.683、4.490)eV和Urbach能(2.38、2.45、2.94、2.74、3.67)eV。,按比例计算,如表1 结论:通过研究纳米碳化物在聚乙烯醇中的消光和吸收系数、直接和间接光能隙、厄巴赫能等光学特性,发现在聚乙烯醇中加入纳米碳化物,消光和吸收系数厄巴赫能增加,表明直接和间接能隙缩小。这表明纳米复合材料的光学特性得到了改善。
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