Progress and Perspectives on Promising Covalent-Organic Frameworks (COFs) Materials for Energy Storage Capacity

IF 7 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chemical record Pub Date : 2023-11-20 DOI:10.1002/tcr.202300285
Umer Shahzad, Hadi M. Marwani, Mohsin Saeed, Abdullah M. Asiri, Md. Reazuddin Repon, Raed H. Althomali, Mohammed M. Rahman
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Abstract

In recent years, a new class of highly crystalline advanced permeable materials covalent-organic frameworks (COFs) have garnered a great deal of attention thanks to their remarkable properties, such as their large surface area, highly ordered pores and channels, and controllable crystalline structures. The lower physical stability and electrical conductivity, however, prevent them from being widely used in applications like photocatalytic activities and innovative energy storage and conversion devices. For this reason, many studies have focused on finding ways to improve upon these interesting materials while also minimizing their drawbacks. This review article begins with a brief introduction to the history and major milestones of COFs development before moving on to a comprehensive exploration of the various synthesis methods and recent successes and signposts of their potential applications in carbon dioxide (CO2) sequestration, supercapacitors (SCs), lithium-ion batteries (LIBs), and hydrogen production (H2-energy). In conclusion, the difficulties and potential of future developing with highly efficient COFs ideas for photocatalytic as well as electrochemical energy storage applications are highlighted.

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共价有机框架(COFs)储能材料研究进展与展望
近年来,共价有机框架(COFs)作为一类新型的高结晶性先进渗透材料,由于其具有较大的表面积、高度有序的孔和通道以及可控制的晶体结构等显著的性能而受到了广泛的关注。然而,较低的物理稳定性和导电性阻碍了它们在光催化活性和创新能量存储和转换装置等应用中的广泛应用。出于这个原因,许多研究都集中在寻找方法来改进这些有趣的材料,同时尽量减少它们的缺点。这篇综述文章首先简要介绍了COFs的历史和发展的主要里程碑,然后全面探讨了各种合成方法和最近的成功和它们在二氧化碳(CO2)封存、超级电容器(SCs)、锂离子电池(lib)和制氢(H2 -能源)方面的潜在应用。最后,强调了高效COFs在光催化和电化学储能应用方面的难点和未来发展潜力。
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来源期刊
Chemical record
Chemical record 化学-化学综合
CiteScore
11.00
自引率
3.00%
发文量
188
审稿时长
>12 weeks
期刊介绍: The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.
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