Effect of ludwigite on sintering and metallurgical properties

Hua-bin Gao, Zhenggen Liu, Mansheng Chu, Jue Tang
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Abstract

Ludwigite is a multi-element coexisting iron ore. Through the sinter pot experiment, the effect of ludwigite on the metallurgical properties of the sinter is studied, and its action mechanism is revealed combined with X-ray diffraction (XRD) analysis. The appropriate amount of ludwigite is obtained on the evaluation mechanism of softening and melting properties of the sinter, which provides theoretical guidance for practical production. The results show that with the increase of the amount of ludwigite, the yield, vertical sintering speed, and drum index in the metallurgical properties of the sinter show a gradual downward trend, and the low-temperature reduction pulverization index RDI+3.15 shows a gradual upward trend. The addition of ludwigite is conducive to the formation of calcium ferrite and promotes the activity of MgO. The addition of excessive ludwigite will lead to the formation of Mg2B2O5 and Ca3B2O6, Slag phase is formed. With the increase of the proportion of ludwigite, the melting range of the sinter is slightly widened, and the permeability is improved first and then reduced. Under this ore blending condition, ludwigite resources can be added and used in sintering batching, and the proportion shall not exceed 6%.
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褐铁矿对烧结和冶金性能的影响
路德维希铁矿是一种多元素共存铁矿,通过烧结罐试验,研究了路德维希矿对烧结矿冶金性能的影响,并结合x射线衍射(XRD)分析揭示了其作用机理。通过对烧结矿软化和熔融性能评价机理的研究,获得了合适的路德辉石用量,为实际生产提供了理论指导。结果表明:随着路德维希矿用量的增加,烧结矿的冶金性能中产率、垂直烧结速度、转鼓指数呈逐渐下降趋势,低温还原粉化指数RDI+3.15呈逐渐上升趋势。铁辉石的加入有利于铁酸钙的形成,提高了氧化镁的活性。过量的路德辉石的加入会导致Mg2B2O5和Ca3B2O6的形成,形成渣相。随着铁辉石掺量的增加,烧结矿的熔融范围略有扩大,渗透率先提高后降低。在此配矿条件下,可添加褐铁矿资源用于烧结配料,比例不得超过6%。
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